2433-56-9

Basic information

• Product Name: 1-HYDROXY-PHENANTHRENE
• Synonyms: 1-HYDROXY-PHENANTHRENE;1-Phenanthrol;phenanthrol;1-Phenanthrenol;NSC 44471;Phenanthren-1-ol
• CAS NO: 2433-56-9
• Molecular Formula: C₁₄H₁₀O
• Molecular Weight: 194.23
• Product Categories: Various Metabolites and Impurities;Intermediates & Fine Chemicals;Metabolites & Impurities;Pharmaceuticals;Aromatics
• Mol File: 2433-56-9.mol
• Article Data: 5

Chemical Properties

• Melting Point: 144-147°C
• Boiling Point: 404.5 °C at 760 mmHg
• Flash Point: 197.7 °C
• Appearance: /
• Density: 1.244 g/cm³
• Vapor Pressure: 4.02E-07mmHg at 25°C
• Refractive Index: 1.753
• Storage Temp.: Refrigerator
• Solubility: Chloroform (Slightly), Ethanol (Slightly), Ethyl Acetate (Slightly), Methanol (S
• PKA: 9.40±0.30(Predicted)
• CAS DataBase Reference: 1-HYDROXY-PHENANTHRENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-HYDROXY-PHENANTHRENE(2433-56-9)
• EPA Substance Registry System: 1-HYDROXY-PHENANTHRENE(2433-56-9)

Safety Data

• Hazardous Substances Data: 2433-56-9(Hazardous Substances Data)

Usage

Description

1-HYDROXY-PHENANTHRENE is a metabolite of Phenanthrene, which is a pale brown solid. It is a chemical compound derived from the parent compound Phenanthrene, which is a polycyclic aromatic hydrocarbon (PAH) consisting of four fused rings.

Uses

Used in Chemical Synthesis:
1-HYDROXY-PHENANTHRENE is used as a chemical intermediate for the synthesis of various organic compounds. Its unique structure allows it to be a versatile building block in the creation of different molecules, particularly those with pharmaceutical or industrial applications.
Used in Pharmaceutical Industry:
1-HYDROXY-PHENANTHRENE is used as a key component in the development of new drugs. Its chemical properties make it a valuable candidate for the design and synthesis of novel pharmaceuticals, potentially leading to the discovery of new treatments for various diseases and conditions.
Used in Environmental Applications:
1-HYDROXY-PHENANTHRENE, being a metabolite of Phenanthrene, can be utilized in environmental studies and remediation efforts. Understanding its role in the degradation of PAHs can help in developing strategies to mitigate the environmental impact of these pollutants.
Used in Research and Development:
1-HYDROXY-PHENANTHRENE serves as a valuable compound for research purposes, particularly in the fields of organic chemistry, materials science, and pharmacology. Its unique properties and potential applications make it an interesting subject for further investigation and development.

InChI:InChI=1/C14H10O/c15-14-7-3-6-12-11-5-2-1-4-10(11)8-9-13(12)14/h1-9,15H

Upstream product

• 110-00-9 furan 
• 126613-08-9 trifluoromethanesulfonic acid 1-bromonaphthalen-2-yl ester 
• 85-01-8 phenanthrene 

Downstream Products

• 33929-60-1 4-Amino-1-oxy-phenanthren 
• 238-04-0 naphtho[1,2-k]fluoranthene 
• 33929-61-2 1,4-diacetoxy-phenanthrene 
• 7468-83-9 1-(1-hydroxy-[2]phenanthryl)-propan-1-one 
• 834-99-1 1-methoxyphenanthrene 
• 573-12-6 phenanthrene 1,2-quinone 

Relevant articles and documents

Br?nsted Acid-Catalyzed Carbonyl-Olefin Metathesis: Synthesis of Phenanthrenes via Phosphomolybdic Acid as a Catalyst

Compared with the impressive achievements of catalytic carbonyl-olefin metathesis (CCOM) mediated by Lewis acid catalysts, exploration of the CCOM through Br?nsted acid-catalyzed approaches remains quite challenging. Herein, we disclose a synthetic protocol for the construction of a valuable polycycle scaffold through the CCOM with the inexpensive, nontoxic phosphomolybdic acid as a catalyst. The current annulations could realize carbonyl-olefin, carbonyl-alcohol, and acetal-alcohol in situ CCOM reactions and feature mild reaction conditions, simple manipulation, and scalability, making this strategy a promising alternative to the Lewis acid-catalyzed COM reaction.

Isomerization of 7-oxabenzonorbornadienes into naphthols catalyzed by [RuCl2(CO)3]2

(Chemical Equation Presented) Ruthenium-catalyzed isomerization of 7-oxanorbornadienes into naphthols was investigated. Among the various ruthenium catalysts tested, [RuCl2(CO)3]2 gave the highest yields in the isomerizati

Stereochemical and Mechanistic Aspects of Sulphoxide, Epoxide, Arene Oxide, and Phenol Formation by Photochemical Oxygen Atom Transfer from Aza-aromatic N-Oxides

Stereoselectivity and relative yields are determined for the sulphoxide formation resulting from the u.v. irradiation of a range of aza-aromatic N-oxides in the presence of cyclic thioethers.A comparison is made with the results of oxidation by oxaziridines and by mono-oxygenase enzymes present in the fungus Aspergillus niger.The photochemical oxidation results are consistent with a transition state involving an oxaziridine intermediate where partial bonding of the oxygen atom to the ring nitrogen atom is maintained during the oxygen transfer process.Photolysis of aza-aromatic N-oxides in the presence of cis- and trans-olefins yields epoxides. cis-4-Methylpent-2-ene yielded both cis and trans-epoxides in almost equal proportions indicating that the oxygen atom addition to a carbon-carbon bond in this system is non-concerted.The photochemically induced oxygenation of perdeuteriated aromatic substrates provides no evidence for direct insertion of an oxygen atom into an aromatic carbon-hydrogen bond.Addition of an oxygen atom to form an epoxide (arene oxide) intermediate in this system is evidenced by the NIH shift in a wide range of aromatic substrates, and by the detection of arene oxide intermediates (and their isomeric phenols) from naphthalene and phenanthrene.