24375-05-1

Basic information

• Product Name: N,N-dichloro-adamantan-1-amine
• Synonyms: N,N-dichloro-adamantan-1-amine
• CAS NO: 24375-05-1
• Molecular Weight: 220.142
• Mol File: 24375-05-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-dichloro-adamantan-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dichloro-adamantan-1-amine(24375-05-1)
• EPA Substance Registry System: N,N-dichloro-adamantan-1-amine(24375-05-1)

Safety Data

• Hazardous Substances Data: 24375-05-1(Hazardous Substances Data)

Upstream product

• 24375-06-2 1-(Chloroamino)adamantane 

Downstream Products

• 935-56-8 1-chloroadamantane 
• 16104-50-0 1,3-dichloroadamantane 

Relevant articles and documents

Thermolysis of N,N-Dihalo Derivatives of Bridgehead and Neopentylamines to the Corresponding Halides.

N,N-Dihalo derivatives of (1-adamantyl)- and neopentylamine are converted to the corresponding alkyl halides in excellent yields (88-94percent) during GLC at 155-330 deg C.Decomposition apparently occurs by an SNi mechanism or by intramolecular homolytic cleavage.Intermolecular radical and free-ion reactions are eliminated from consideration because of the absence of radical-derived or rearranged products.Steric factors are deemed important in the neopentyl case since pyrolysis of N,N-dihaloamine gave the corresponding carbonitrile in excellent yield(90-97percent). 1-(Haloamino)adamantanes gave fair amounts of 1-haloadamantanes (30-38percent). 1-(Acetylamino)- and 1-(ethylchloroamino)adamantane yielded 1-chloroadamantane (10-17percent), the major products being the acetamide (60percent) and the ethylamine (56percent), respectively. 1-(Dihaloamino)adamantanes were converted to 1-haloadamantanes by neat (64-70percent) or solution (30-41percent) pyrolysis.