244049-60-3

Basic information

• Product Name: diethyl-carbamic acid 4-heptadecafluorooctyl-phenyl ester
• Synonyms: diethyl-carbamic acid 4-heptadecafluorooctyl-phenyl ester
• CAS NO: 244049-60-3
• Molecular Weight: 611.299
• Mol File: 244049-60-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diethyl-carbamic acid 4-heptadecafluorooctyl-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl-carbamic acid 4-heptadecafluorooctyl-phenyl ester(244049-60-3)
• EPA Substance Registry System: diethyl-carbamic acid 4-heptadecafluorooctyl-phenyl ester(244049-60-3)

Safety Data

• Hazardous Substances Data: 244049-60-3(Hazardous Substances Data)

Upstream product

• 88-10-8 N,N-diethylcarbamyl chloride 
• 80804-82-6 4-(n-heptadecafluorooctyl)phenol 

Downstream Products

• 244049-59-0 5-(n-heptadecafluorooctyl)salicylaldehyde 

Relevant articles and documents

Enantioselective catalysis in fluorinated media - Synthesis and properties of chiral perfluoroalkylated (salen)manganese complexes

Chiral (salen)manganese complexes, which are selectively soluble in perfluorocarbons, were synthesized and tested as epoxidation catalysts in fluorous-organic two-phase systems. The immiscibility of the perfluorocarbons with regular organic solvents allowed a quick and effective separation of the catalyst from the products. These unprecedented perfluoroalkylated salen complexes were found to be efficient and chemoselective catalysts in the presence of several oxygen donors, but enantioselectivities were generally poor. An interesting exception to this behaviour was observed in the asymmetric epoxidation of indene that provides indene oxide with 70-92% enantiomeric excess.