244262-69-9

Basic information

• Product Name: allyl-[1-(3,4-difluoro-phenyl)-vinyl]-carbamic acid ethyl ester
• CAS NO: 244262-69-9
• Molecular Weight: 267.275
• Mol File: 244262-69-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: allyl-[1-(3,4-difluoro-phenyl)-vinyl]-carbamic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: allyl-[1-(3,4-difluoro-phenyl)-vinyl]-carbamic acid ethyl ester(244262-69-9)
• EPA Substance Registry System: allyl-[1-(3,4-difluoro-phenyl)-vinyl]-carbamic acid ethyl ester(244262-69-9)

Safety Data

• Hazardous Substances Data: 244262-69-9(Hazardous Substances Data)

Upstream product

• 188345-25-7 3,4-difluoro-N-methoxy-N-methylbenzamide 
• 76903-88-3 3,4-difluorobenzoyl chloride 
• 369-33-5 3',4'-difluoroacetophenone 
• 1609-47-8 diethyl dicarbonate 
• 244263-36-3 Allyl-[1-(3,4-difluoro-phenyl)-eth-(E)-ylidene]-amine 

Relevant articles and documents

A concise route to novel 1-aryl and 1-pyridyl-2-azabicyclo[2.1.1]hexanes

A number of novel 1-aryl and 1-pyridyl-2-azabicyclo[2.1.1]hexane derivatives were prepared by an intramolecular [2+2] photocycloaddition in the presence of acetophenone as the sensitizer. Substitution of the azabicyclo[2.1.1]hexane ring was accomplished by appropriate choice of the heteroaryl ketone and allylamine starting materials. Several aryl 9a-e, g and pyridyl analogs 9h-l were prepared by this method. The structures of 9a and 9i were verified by X-ray crystallography. Several of the photoproducts 9 were converted into the corresponding N-Me and N-H 2,4-methanonicotine analogs 4 by reduction or hydrolysis of the N-carboethoxy group.