2444-19-1

Basic information

• Product Name: 4-HYDROXYPHENYL BENZOATE
• Synonyms: 1,4-Diphenol, 1-benzoate;4-HYDROXYPHENYL BENZOATE;P-HYDROXYPHENYL BENZOATE;Benzoic acid 4-hydroxyphenyl ester~Hydroquinone monobenzoate;Benzoic Acid 4-Hydroxyphenyl Ester;hydroquinone monobenzoate;1,4-Benzenediol 1-benzoate;p-Hydroquinone monobenzoate
• CAS NO: 2444-19-1
• Molecular Formula: C₁₃H₁₀O₃
• Molecular Weight: 214.22
• EINECS: 219-479-4
• Product Categories: Aromatic Esters
• Mol File: 2444-19-1.mol
• Article Data: 27

Chemical Properties

• Melting Point: 164-165°C
• Boiling Point: 376.6 °C at 760 mmHg
• Flash Point: 164.7 °C
• Appearance: /
• Density: 1.25 g/cm³
• Vapor Pressure: 3.3E-06mmHg at 25°C
• Refractive Index: 1.615
• Storage Temp.: 2-8°C
• PKA: 9.59±0.26(Predicted)
• BRN: 2050596
• CAS DataBase Reference: 4-HYDROXYPHENYL BENZOATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-HYDROXYPHENYL BENZOATE(2444-19-1)
• EPA Substance Registry System: 4-HYDROXYPHENYL BENZOATE(2444-19-1)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 2444-19-1(Hazardous Substances Data)

Usage

Description

4-Hydroxyphenyl Benzoate, also known as para-hydroxybenzene benzoate, is an organic compound that serves as a versatile intermediate in the chemical industry. It is characterized by its aromatic structure, which includes a hydroxyl group and a benzoate group, providing it with unique chemical properties and reactivity.

Uses

Used in Chemical Synthesis:
4-Hydroxyphenyl Benzoate is used as a key intermediate in the synthesis of various chemical compounds. Its aromatic structure and functional groups make it a valuable building block for creating a wide range of products.
Used in Insecticide Production:
4-Hydroxyphenyl Benzoate is used as a crucial component in the production of the insecticide Pyridalyl (P997113). Its incorporation into the insecticide formulation contributes to its effectiveness in controlling pests and protecting crops.

InChI:InChI=1/C13H10O3/c14-11-6-8-12(9-7-11)16-13(15)10-4-2-1-3-5-10/h1-9,14H

Upstream product

• 93-99-2 benzoic acid phenyl ester 
• 14210-97-0 1,4-dibenzoyloxybenzene 
• 7732-18-5 water 
• 98-88-4 benzoyl chloride 
• 123-31-9 hydroquinone 
• 64-17-5 ethanol 
• 65-85-0 benzoic acid 
• 6411-34-3 4-allyloxyphenol 
• 37592-20-4 1,4-bis(allyloxy)benzene 
• 88561-74-4 4-(allyloxy)phenyl benzoate 
• 100-52-7 benzaldehyde 
• 106-51-4 p-benzoquinone 
• 74206-92-1 carbonic acid benzyl ester-(4-hydroxy-phenyl ester) 
• 103-16-2 4-Benzyloxyphenol 

Downstream Products

• 5379-30-6 4-Benzoyloxy-2-phenylazo-phenol 
• 13985-43-8 4-hydroxy-3-nitrophenyl benzoate 
• 108955-74-4 phosphoric acid mono-(4-benzoyloxy-phenyl ester) 
• 58069-02-6 2.6-dinitro-hydroquinone-4-benzoate 
• 123-31-9 hydroquinone 
• 16090-33-8 2-nitrohydroquinone 
• 225529-40-8 4-benzoyloxy phenyl acetate 
• 88561-74-4 4-(allyloxy)phenyl benzoate 
• 109591-22-2 phosphoric acid diethyl ester-(4-benzoyloxy-phenyl ester) 
• 380153-99-1 4-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)phenylbenzoate 
• 125439-41-0 4-(2-quinolinylmethoxy)phenyl benzoate 
• 132239-98-6 2-Benzoyloxy-5-hydroxy-4'-cyano-azobenzene 
• 97971-74-9 (2-hydroxy-5-benzoyloxyphenyl)(phenyl)methanone 
• 569353-65-7 (S)-(+)-4-[1-(2-methyl)octyloxy]phenyl benzoate 

Relevant articles and documents

N,O-Benzyl Protection of Structurally Varied Amines and Phenols Using Wells-Dawson Heteropolyacid Catalyst

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Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes

An efficient and mild catalytic deallylation method of aryl allyl ethers is developed, with commercially available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process is compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway.

An efficient and chemoselective deprotection of aryl tert-butyldimethylsilyl (TBDMS) ethers by NaCN

Phenolic tert-butyldimethylsilyl (TBDMS) ethers can be deprotected to yield phenols in excellent yield using sodium cyanide (NaCN) as catalyst in ethanol. The deprotectation of various phenolic TBDMS ethers were found to be very convenient, fast, high yielding and chemoselective.