24469-13-4

Basic information

• Product Name: 1-(phenylthio)-2-methyl-1-phenyl-1-propene
• Synonyms: 1-(phenylthio)-2-methyl-1-phenyl-1-propene
• CAS NO: 24469-13-4
• Molecular Weight: 240.369
• Mol File: 24469-13-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(phenylthio)-2-methyl-1-phenyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(phenylthio)-2-methyl-1-phenyl-1-propene(24469-13-4)
• EPA Substance Registry System: 1-(phenylthio)-2-methyl-1-phenyl-1-propene(24469-13-4)

Safety Data

• Hazardous Substances Data: 24469-13-4(Hazardous Substances Data)

Upstream product

• 884-09-3 phenyl thiobenzoate 
• 62461-01-2 4-methyl-N'-(2-methyl-1-phenylpropylidene)benzenesulfonohydrazide 
• 16666-80-1 triphenylphosphonio-1-methylethanide 
• 108-98-5 thiophenol 
• 611-70-1 phenyl isopropyl ketone 

Downstream Products

• 538-93-2 1-phenyl-2-methylpropane 
• 768-49-0 (2-methyl-1-propenyl)-benzene 

Relevant articles and documents

Pd-Catalyzed Alkenyl Thioether Synthesis from Thioesters and N-Tosylhydrazones

A Pd-catalyzed alkenyl thioether synthesis was achieved using thioesters and N-tosylhydrazones as starting materials. The thioester acted as an efficient "sulfur source" for catalytic C-S bond formation using N-tosylhydrazone. This method gave Z-alkenyl thioethers with high diastereoselectivity (up to 99:1 diastereomeric ratio). This transformation displayed a wide functional group tolerance and was successfully applied to the late-stage derivatization of a pharmaceutical molecule to the corresponding alkenyl thioether.