245115-69-9Relevant articles and documents
Facile amide formation via S -nitrosothioacids
Pan, Jia,Devarie-Baez, Nelmi O.,Xian, Ming
supporting information; experimental part, p. 1092 - 1094 (2011/04/25)
Here we report a novel amide bond formation strategy from simple thioacid and amine starting materials. The reaction is mediated by unstable but very reactive S-nitrosothioacid intermediates. This fast reaction under mild conditions should be useful in synthesis.(Figure Presented)
Total synthesis of the putative structure of the marine metabolite trunkamide A
Wipf, Peter,Uto, Yoshikazu
, p. 5165 - 5169 (2007/10/03)
The structure assigned to trunkamide A, a cycloheptapeptide alkaloid isolated from the colonial ascidian Lissoclinum sp., was prepared via segment condensations and an efficient oxazoline-thiazoline interconversion. The novel reverse prenylated serine and