Welcome to LookChem.com Sign In|Join Free

CAS

  • or

245653-52-5

Post Buying Request

245653-52-5 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

245653-52-5 Usage

Description

7-(4-tert-Butylphenyl)-2-methyl-1H-indene is an organic compound characterized by its unique molecular structure, which features a tert-butylphenyl group attached to the 7th position of an indene molecule, with a methyl group at the 2nd position. 7-(4-tert-Butylphenyl)-2-methyl-1H-indene is known for its specific chemical properties and potential applications in various industries.

Uses

Used in Polymer Industry:
7-(4-tert-Butylphenyl)-2-methyl-1H-indene is used as a comonomer in the polymerization process for the preparation of propylene homopolymer. Its incorporation into the polymerization process enhances the properties of the resulting polymer, such as its thermal stability, mechanical strength, and resistance to degradation.
Used in Catalyst Preparation:
In the polymerization process, 7-(4-tert-Butylphenyl)-2-methyl-1H-indene is used in conjunction with a catalyst system comprising metallocene, borate, and aluminoxane. The presence of this compound in the catalyst system contributes to the efficiency and selectivity of the polymerization reaction, leading to the production of high-quality propylene homopolymers with desired characteristics.

Check Digit Verification of cas no

The CAS Registry Mumber 245653-52-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,4,5,6,5 and 3 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 245653-52:
(8*2)+(7*4)+(6*5)+(5*6)+(4*5)+(3*3)+(2*5)+(1*2)=145
145 % 10 = 5
So 245653-52-5 is a valid CAS Registry Number.
InChI:InChI=1/C20H22/c1-14-12-16-6-5-7-18(19(16)13-14)15-8-10-17(11-9-15)20(2,3)4/h5-12H,13H2,1-4H3

245653-52-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name 7-(4-tert-Butylphenyl)-2-methyl-1H-indene

1.2 Other means of identification

Product number -
Other names 7-(4-(tert-Butyl)phenyl)-2-methyl-1H-indene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:245653-52-5 SDS

245653-52-5Synthetic route

4(7)-bromo-2-methyl-1(3)H-indene
880652-93-7

4(7)-bromo-2-methyl-1(3)H-indene

4-tert-butylmagnesium bromide
63488-10-8

4-tert-butylmagnesium bromide

2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

Conditions
ConditionsYield
With (IPr)NiCl2PPh3 In tetrahydrofuran at 20℃; for 0.833333h; Reflux;96%
4-tert-butyl-2',3'-bis(chloromethyl)biphenyl
683229-41-6

4-tert-butyl-2',3'-bis(chloromethyl)biphenyl

acetic acid methyl ester
79-20-9

acetic acid methyl ester

A

2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

B

4-(4-(tert-butyl)phenyl)-2-methyl-1H-indene

4-(4-(tert-butyl)phenyl)-2-methyl-1H-indene

Conditions
ConditionsYield
Stage #1: 4-tert-butyl-2',3'-bis(chloromethyl)biphenyl With magnesium-anthracene In tetrahydrofuran at 0 - 20℃; for 1h;
Stage #2: acetic acid methyl ester In tetrahydrofuran at 0 - 20℃;
Stage #3: toluene-4-sulfonic acid In toluene for 1.5h; Heating / reflux;
A 28%
B 28%
4(7)-bromo-2-methyl-1(3)H-indene
880652-93-7

4(7)-bromo-2-methyl-1(3)H-indene

1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

A

2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

B

4-(4-(tert-butyl)phenyl)-2-methyl-1H-indene

4-(4-(tert-butyl)phenyl)-2-methyl-1H-indene

Conditions
ConditionsYield
Stage #1: 1-bromo-4-tert-butylbenzene With magnesium In tetrahydrofuran Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: 4(7)-bromo-2-methyl-1(3)H-indene With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](triphenylphosphine)nickel(II) dichloride In tetrahydrofuran for 0.833333h; Inert atmosphere; Schlenk technique; Glovebox; Reflux; Overall yield = 96 %; Overall yield = 93.8 g;
2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

(6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)(chloro)dimethylsilane
1417536-78-7

(6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)(chloro)dimethylsilane

(6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)[4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl] dimethylsilane
1417536-81-2

(6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)[4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl] dimethylsilane

Conditions
ConditionsYield
Stage #1: 7-(4-tert-butylphenyl)-2-methyl-1H-indene With n-butyllithium In diethyl ether; hexane at -78 - 20℃; for 1h;
Stage #2: With copper(l) cyanide In diethyl ether at 20℃;
Stage #3: (6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)(chloro)dimethylsilane In diethyl ether at -70℃;
91%
Stage #1: 7-(4-tert-butylphenyl)-2-methyl-1H-indene With n-butyllithium In diethyl ether; hexane at -78 - 20℃; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: With copper(l) cyanide In diethyl ether; hexane at -60 - -20℃; for 1h; Inert atmosphere; Schlenk technique; Glovebox;
Stage #3: (6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)(chloro)dimethylsilane In diethyl ether; hexane at -70 - 20℃; Inert atmosphere; Schlenk technique; Glovebox;
91%
In water
2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

chloro [4-(3,5-di-tert-butylphenyl)-7-methoxy-2-methyl-1H-inden-1-yl]dimethylsilane
1417537-03-1

chloro [4-(3,5-di-tert-butylphenyl)-7-methoxy-2-methyl-1H-inden-1-yl]dimethylsilane

[2-methyl-4-(4-tert-Butylphenyl)-1H-inden-1-yl]-[2-methyl-4-(3,5-di-tert-butylphenyl)-7-methoxy-1H-inden-1-yl]dimethylsilane
1613522-83-0

[2-methyl-4-(4-tert-Butylphenyl)-1H-inden-1-yl]-[2-methyl-4-(3,5-di-tert-butylphenyl)-7-methoxy-1H-inden-1-yl]dimethylsilane

Conditions
ConditionsYield
In water90%
In water90%
2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

(6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)(chloro)dimethylsilane
1417536-78-7

(6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)(chloro)dimethylsilane

[6-tert-Butyl-4-(3,5-di-tert-butylphenyl)-5-methoxy-2-methyl-1H-inden-1-yl] [4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl]dimethylsilane
1417537-12-2

[6-tert-Butyl-4-(3,5-di-tert-butylphenyl)-5-methoxy-2-methyl-1H-inden-1-yl] [4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl]dimethylsilane

Conditions
ConditionsYield
Stage #1: 7-(4-tert-butylphenyl)-2-methyl-1H-indene With n-butyllithium In diethyl ether; hexane at -40 - 20℃;
Stage #2: With copper(l) cyanide In diethyl ether at -40 - 20℃;
Stage #3: (6-tert-butyl-5-methoxy-2-methyl-4-phenyl-1H-inden-1-yl)(chloro)dimethylsilane
80%
2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

chloro [6-isopropyl-2-methyl-5-(pentafluorophenoxy)-4-phenyl-1H-inden-1-yl] dimethylsilane
1417536-91-4

chloro [6-isopropyl-2-methyl-5-(pentafluorophenoxy)-4-phenyl-1H-inden-1-yl] dimethylsilane

[4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl][6-isopropyl-2-methyl-5-(pentafluorophenoxy)-4-phenyl-1H-inden-1-yl] dimethylsilane

[4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl][6-isopropyl-2-methyl-5-(pentafluorophenoxy)-4-phenyl-1H-inden-1-yl] dimethylsilane

Conditions
ConditionsYield
Stage #1: 7-(4-tert-butylphenyl)-2-methyl-1H-indene With n-butyllithium In diethyl ether; hexane at -40 - 20℃; for 1h;
Stage #2: With copper(l) cyanide In diethyl ether; water at 20℃;
Stage #3: chloro [6-isopropyl-2-methyl-5-(pentafluorophenoxy)-4-phenyl-1H-inden-1-yl] dimethylsilane
53%
2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

[2-methyl-4-(3',5'-di-tert-butylphenyl)-6-tert-butyl-5-methoxy-1H-inden-1-yl] chlorodimethylsilane
1417537-11-1

[2-methyl-4-(3',5'-di-tert-butylphenyl)-6-tert-butyl-5-methoxy-1H-inden-1-yl] chlorodimethylsilane

[6-tert-Butyl-4-(3,5-di-tert-butylphenyl)-5-methoxy-2-methyl-1H-inden-1-yl] [4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl]dimethylsilane
1417537-12-2

[6-tert-Butyl-4-(3,5-di-tert-butylphenyl)-5-methoxy-2-methyl-1H-inden-1-yl] [4-(4-tert-butylphenyl)-2-methyl-1H-inden-1-yl]dimethylsilane

Conditions
ConditionsYield
In hexane; dichloromethane; water
2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

[2-methyl-4-(3,5-di-tert-butylphenyl)-6-tert-butyl-1H-inden-1-yl] (chloro)dimethylsilane
1613522-92-1

[2-methyl-4-(3,5-di-tert-butylphenyl)-6-tert-butyl-1H-inden-1-yl] (chloro)dimethylsilane

[2-methyl-4-(3,5-di-tert-butylphenyl)-6-tert-Butyl-1H-inden-1-yl] [2-methyl-4-(4-tert-butylphenyl)-1H-inden-1-yl] dimethylsilane
1613522-93-2

[2-methyl-4-(3,5-di-tert-butylphenyl)-6-tert-Butyl-1H-inden-1-yl] [2-methyl-4-(4-tert-butylphenyl)-1H-inden-1-yl] dimethylsilane

Conditions
ConditionsYield
In dichloromethane; water
In dichloromethane; water
2-methyl-7-(4-tert-butylphenyl)-1H-indene
245653-52-5

2-methyl-7-(4-tert-butylphenyl)-1H-indene

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

[2-methyl-4-(4-tert-butylphenyl)-1H-inden-1-yl](chloro)dimethylsilane
324534-23-8

[2-methyl-4-(4-tert-butylphenyl)-1H-inden-1-yl](chloro)dimethylsilane

Conditions
ConditionsYield
In tetrahydrofuran; toluene
In tetrahydrofuran; toluene

245653-52-5Relevant articles and documents

CATALYSTS

-

Page/Page column 66, (2014/07/08)

An asymmetric complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R2 and R2' are each independently a C1-C20 hydrocarbyl radical; R5' is a C1-20 hydrocarbyl group; R5 is hydrogen, or a C1-20 hydrocarbyl group; R6 is a non tertiary C1-10 alkyl group or C6-10-aryl group or C7-10 arylalkyl group or ZR3; R6' is a tertiary C4-20 alkyl group; Z is O or S; R3 is a C1-20 hydrocarbyl group optionally substituted with halo; Ar is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R1; Ar' is an aryl or heteroaryl group having up to 20 carbon atoms optionally substituted by one or more groups R1; each R1 is a C1-20 hydrocarbyl group or two R1 groups on adjacent carbon atoms taken together can form a fused 5 or 6 membered ring with the Ar group, said ring being itself optionally substituted with one or more groups R4; and each R4 is a C1-20 hydrocarbyl group.

PREPARATION OF SUBSTITUTED INDENES

-

Example 4, (2010/02/06)

The present invention relates to a simple process for preparing specifically substituted indenes of formula (I) or (Ia) to compounds of formula (II) serving as starting materials and to the use of the compounds of formula (II) as starting materials for the synthesis of substituted indenes.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 245653-52-5