245736-18-9

Basic information

• Product Name: 5-Hexen-2-ol, 1-(triphenylmethoxy)-, (2R)-
• CAS NO: 245736-18-9
• Molecular Formula: C25H26O2
• Molecular Weight: 358.48
• Mol File: 245736-18-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-Hexen-2-ol, 1-(triphenylmethoxy)-, (2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexen-2-ol, 1-(triphenylmethoxy)-, (2R)-(245736-18-9)
• EPA Substance Registry System: 5-Hexen-2-ol, 1-(triphenylmethoxy)-, (2R)-(245736-18-9)

Safety Data

• Hazardous Substances Data: 245736-18-9(Hazardous Substances Data)

Upstream product

• 65291-30-7 (R)-(+)-trityl glycidyl ether 
• 1730-25-2 allylmagnesium bromide 
• 7103-09-5 4-but-1-enylmagnesium bromide 

Downstream Products

• 925210-04-4 (S)-tert-butyl tosyl(1-(trityloxy)hex-5-en-2-yl)carbamate 
• 245736-60-1 C₇₅H₁₀₈N₂O₁₆Si₂ 
• 245736-69-0 C₆₉H₉₄N₂O₁₆Si 
• 245736-72-5 C₆₂H₈₈N₂O₁₆Si 
• 245736-73-6 C₆₂H₈₆N₂O₁₅Si 
• 245736-59-8 2-{6-[7-(4-benzyl-2-oxo-oxazolidine-3-carbonyl)-4-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-5,9-dimethyl-6-oxo-undec-10-ynyl]-2-methoxy-4-methoxycarbonylmethylene-tetrahydro-pyran-2-yl}-propionic acid benzyl ester 
• 245736-71-4 C₅₃H₇₅NO₁₃Si 
• 245736-58-7 (S)-2-{(2S,6R)-6-[(1R,4R,5R,7S,9R)-7-((S)-4-Benzyl-2-oxo-oxazolidine-3-carbonyl)-4-hydroxy-1-(4-methoxy-benzyloxy)-5,9-dimethyl-6-oxo-undec-10-ynyl]-2-methoxy-4-[1-methoxycarbonyl-meth-(E)-ylidene]-tetrahydro-pyran-2-yl}-propionic acid benzyl ester 
• 245736-77-0 C₄₄H₆₂O₁₃ 

Relevant articles and documents

Construction of Iterative Tetrahydrofuran Ring Units and Total Synthesis of (+)-Goniocin

Cytotoxic acetogenin (+)-goniocin has been synthesized in 17 steps from (R)-O-tritylglycidol. The core structure of the contiguous C22-C10 threo-trans-threo-trans-threo-trans-tris-tetrahydrofuran (THF) ring involving an iterative THF-ring unit was synthesized. An iterative THF ring unit was constructed from an alkenyl-substituted THF ring in four steps including a Pd(II)-catalyzed ring-closing reaction and cross-metathesis. This method is general and allows the preparation of both trans-threo-trans- and trans-threo-cis-THF ring units flexibly.

Synthesis and absolute stereochemical assignment of (+)-miyakolide

The first total synthesis of the marine macrolide miyakolide has been achieved, and its absolute stereochemistry has been determined. The carbon skeleton is assembled in a convergent fashion from three fragments via esterification, [3 + 2] dipolar cycload