24595-58-2Relevant articles and documents
Brown,C.A.,Coleman,R.A.
, p. 2328 - 2329 (1979)
Method for efficiently synthesizing 1,6-diene-3-ketone derivatives
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Paragraph 0025-0026; 0033-0035, (2021/01/29)
The invention discloses a method for efficiently synthesizing 1,6-diene-3-ketone derivatives, which comprises the following steps: in an organic solvent system, taking a compound represented by a formula 2 as a raw material, carrying out stirring reflux r
Electrochemically enabled rhodium-catalyzed [4 + 2] annulations of arenes with alkynes
Chen, Jia-Yi,Li, Ming,Li, Rui-Tao,Ma, Qiang,Ni, Shao-Fei,Wang, Zi-Chen,Wen, Li-Rong,Zhang, Lin-Bao
supporting information, p. 9515 - 9522 (2021/12/09)
Herein, electrochemically driven, Rh(iii)-catalyzed regioselective annulations of arenes with alkynes have been established. The strategy, combining the use of a rhodium catalyst with electricity, not only avoids the need for using a stoichiometric amount of external oxidant, but also ensures that the transformations proceed under mild and green conditions, which enable broad functional group compatibility with a variety of substrates, including drugs and pharmaceutical motifs. Moreover, the electrolysis reaction was made operationally simple by employing an undivided cell, and proceeds efficiently in aqueous solution in air. This journal is