2469-18-3

Basic information

• Product Name: 2,3-Dihydro-α-methyl-1,4-benzodioxin-2-methanamine
• Synonyms: 2,3-Dihydro-α-methyl-1,4-benzodioxin-2-methanamine;1-(2,3-dihydro-1,4-benzodioxin-3-yl)ethanamine
• CAS NO: 2469-18-3
• Molecular Formula: C₁₀H₁₃NO₂
• Molecular Weight: 179.21572
• Mol File: 2469-18-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 273.8°Cat760mmHg
• Flash Point: 129.4°C
• Appearance: /
• Density: 1.136g/cm³
• Vapor Pressure: 0.0056mmHg at 25°C
• Refractive Index: 1.544
• CAS DataBase Reference: 2,3-Dihydro-α-methyl-1,4-benzodioxin-2-methanamine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-Dihydro-α-methyl-1,4-benzodioxin-2-methanamine(2469-18-3)
• EPA Substance Registry System: 2,3-Dihydro-α-methyl-1,4-benzodioxin-2-methanamine(2469-18-3)

Safety Data

• Hazardous Substances Data: 2469-18-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H13NO2/c1-7(11)10-6-12-8-4-2-3-5-9(8)13-10/h2-5,7,10H,6,11H2,1H3

Upstream product

• 3663-80-7 1,4-benzodioxane-2-carboxylic acid 

Downstream Products

• 69766-28-5 2-<1-Morpholino-aethyl>-1,4-benzodioxan 
• 57047-95-7 C₂₄H₂₃NO₃ 

Relevant articles and documents

Silver-Catalyzed Radical Transformation of Aliphatic Carboxylic Acids to Oxime Ethers

Oximes and oxime ethers are privileged building blocks and can be conveniently converted to ketones, amines, hydroxylamines, and nitriles. We describe the catalytic decarboxylation of aliphatic carboxylic acids to oxime ethers. With AgNO3 as the catalyst, valuable oxime ethers bearing various substituents could be easily obtained. The broad substrate scope, easy accessibility of aliphatic carboxylic acids, and mild reaction conditions make this strategy immediately applicable to the synthesis, late-stage functionalization, and modification of biologically active compounds. Experimental studies show the reaction undergoes a radical process.

Adrenergic neurone blocking agents derived from 1,4-benzodioxan.

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