24695-48-5Relevant articles and documents
(1-Ethoxyvinyl)lithium in the total synthesis of thymine polyoxin C and uracil polyoxin C
Akita, Hiroyuki,Uchida, Kimio,Chen, Cheng Yu.,Kato, Keisuke
, p. 1034 - 1038 (2007/10/03)
A short path synthesis of the ethyl (methyl 2,3-O-isopropylidene-β-D- allofuranosid)uronate (5) and ethyl (methyl 2,3-O-isopropylidene-α-L- talofuranosid)uronate (6) from methyl 2,3-O-isopropylidene-β-D- ribopentodialdo-1,4-furanoside (3) using (1-ethoxyvinyl)lithium and its application to the total synthesis of the pyrimidine nucleosides, thymine polyoxin C (1) and uracil polyoxin C (2), are described.
A short path synthesis of α-hydroxy ester from aldehyde using (1-ethoxyvinyl)lithium and its application to the syntheses of thymine polyoxin c and uracil polyoxin C
Akita, Hiroyuki,Uchida, Kimio,Chen, Cheng Yu
, p. 87 - 90 (2007/10/03)
A short path synthesis of the α-hydroxy esters (4 and 5) from the aldehyde (3) using (1-cthoxyvinyl)lithium and its application to the total syntheses of the pyrimidine nucleoside, thymine polyoxin C (1) and uracil polyoxin C (2), are described.
Synthesis of uracil polyoxin C from uridine
Evina, Claude Mvondo,Guillerm, Georges
, p. 163 - 166 (2007/10/02)
An improved procedure is reported for the asymmetric synthesis of uracil polyoxin C (UPOC) from 2',3'-O-isopropylideneuridine-5'-aldehyde. The methodology described here is based on the highly diastereocontrolled formation of 1-(β-D-allofuranosyl)uracil a