24734-68-7

Basic information

• Product Name: 3-PHENYL-1-PROPANETHIOL
• Synonyms: 3-PHENYLPROPYL MERCAPTAN;3-PHENYL-1-PROPANETHIOL;1-Propanethiol, 3-phenyl-;3-phenyl-propane-1-thiol;3-Phenylpropanethiol;3-Phenylpropylthiol;gamma-Phenylpropyl mercaptan;3-Phenylpropylmercaptane
• CAS NO: 24734-68-7
• Molecular Formula: C₉H₁₂S
• Molecular Weight: 152.26
• EINECS: 246-440-9
• Mol File: 24734-68-7.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 234.76°C (estimate)
• Flash Point: 90.6°C
• Appearance: /
• Density: 1.0100
• Vapor Pressure: 0.0535mmHg at 25°C
• Refractive Index: 1.5494
• PKA: 10.32±0.10(Predicted)
• CAS DataBase Reference: 3-PHENYL-1-PROPANETHIOL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-PHENYL-1-PROPANETHIOL(24734-68-7)
• EPA Substance Registry System: 3-PHENYL-1-PROPANETHIOL(24734-68-7)

Safety Data

• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S37/39:Wear suitable g
• Hazardous Substances Data: 24734-68-7(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

InChI:InChI=1/C9H12S/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6,10H,4,7-8H2

Upstream product

• 89987-96-2 1,2-bis(3-phenylpropyl)disulfane 
• 30134-13-5 S-(3-phenylpropyl) ethanethioate 
• 122-97-4 3-Phenyl-1-propanol 
• 104-52-9 phenylpropyl chloride 
• 132150-34-6 3-phenylpropyl ethanethiolate 
• 114764-11-3 3-phenylpropyl 2-(trimethylsilyl)ethyl sulfide 
• 637-59-2 1-Bromo-3-phenylpropane 
• 105444-69-7 phenylpropyl carbamimidothioate hydrobromide 
• 114764-12-4 (3-Methyldisulfanyl-propyl)-benzene 
• 99168-03-3 dithiocarbamic acid-(3-phenyl-propyl ester) 

Downstream Products

• 30134-10-2 2-(3-phenyl-propylsulfanyl)-propionic acid 
• 38381-15-6 C₂₁H₂₈S₂ 
• 19579-94-3 2-((3-phenylpropyl)thio)acetonitrile 

Relevant articles and documents

Cu-mediated: vs. Cu-free selective borylation of aryl alkyl sulfones

A Cu-catalysed borylation of aryl alkyl sulfones was developed for the high yield synthesis of versatile arylboronic esters using a readily prepared NHC-Cu catalyst. In addition, the selective cleavage of either alkyl(C)-sulfonyl or aryl(C)-sulfonyl bonds

Mo-Based Oxidizers as Powerful Tools for the Synthesis of Thia- and Selenaheterocycles

A highly efficient synthetic protocol for the synthesis of thia- and selenaheterocycles has been developed. By employing a MoCl5-mediated intramolecular dehydrogenative coupling reaction, a broad variety of structural motifs was isolated in yields up to 94 %. The electrophilic key transformation is tolerated by several labile moieties like halides and tertiary alkyl groups. Due to the use of disulfide or diselenide precursors, a high atom efficiency was achieved.

Two-step three-component process for one-pot synthesis of 8-alkylmercaptocaffeine derivatives

A highly efficient, odourless and two-step three-component process for one-pot synthesis of some 8-alkylmercaptocaffeine derivatives has been described. The catalyst-free three-component reaction of alkyl bromides, thiourea, and 8-bromocaffeine gave 8-alkylmercaptocaffeine products in excellent to quantitative yields. In addition, the impact of parameters on sample reaction is discussed.