24748-23-0

Basic information

• Product Name: 3,6,9-TRIETHYL-3,6,9-TRIMETHYL-1,4,7-TRIPEROXYNONANE
• Synonyms: 2,4,5,7,-hexoxonane,3,6,9-triethyl-3,6,9-trimethyl-1;3,6,9-triethyl-3,6,9-trimethyl-1,4,7-triperoxynonane,41%sol.inarom.freemin.spirit;3,6,9-TRIETHYL-3,6,9-TRIMETHYL-1,4,7-TRIPEROXYNONANE;3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane;Trigonox?301;41%Sol.inarom.freemin.spirit;3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane, 41% solution in aromatic free mineral spirit;301
• CAS NO: 24748-23-0
• Molecular Formula: C₁₂H₂₄O₆
• Molecular Weight: 264.31536
• Mol File: 24748-23-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: -20 °C
• Boiling Point: 246.6°C at 760 mmHg
• Flash Point: 58 °C
• Appearance: Clear/Solution
• Density: 0.875
• Vapor Pressure: 0.0422mmHg at 25°C
• Refractive Index: 1.392
• Storage Temp.: Refrigerator (+4°C)
• Water Solubility: 13.1mg/L at 20℃
• CAS DataBase Reference: 3,6,9-TRIETHYL-3,6,9-TRIMETHYL-1,4,7-TRIPEROXYNONANE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6,9-TRIETHYL-3,6,9-TRIMETHYL-1,4,7-TRIPEROXYNONANE(24748-23-0)
• EPA Substance Registry System: 3,6,9-TRIETHYL-3,6,9-TRIMETHYL-1,4,7-TRIPEROXYNONANE(24748-23-0)

Safety Data

• Hazard Codes: Xi-O
• Statements: 7-65-43-38
• Safety Statements: 36/37/39-3/7-26-14A
• Hazardous Substances Data: 24748-23-0(Hazardous Substances Data)

Usage

Chemical Properties

clear solution

InChI:InChI=1/C12H24O6/c1-7-10(4)13-15-11(5,8-2)17-18-12(6,9-3)16-14-10/h7-9H2,1-6H3

Synthetic route

2-Pentanone (107-87-9) + butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + 3-ethyl-3,6,9-trimethyl-6,9-di-(n-propyl)-1,2,4,5,7,8-hexaoxonane + 3,6-diethyl-3,6,9-trimethyl-9-(n-propyl)-1,2,4,5,7,8-hexaoxonane

Conditions	Yield
With sulfuric acid; dihydrogen peroxide at -1 - 1℃; for 2.25h;	A 18.9% B 5.9% C 17.6%

butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0)

Conditions	Yield
With sulfuric acid; dihydrogen peroxide
With sulfuric acid; dihydrogen peroxide at 0℃; for 48h;

sulfuric acid (7664-93-9) + dihydrogen peroxide (7722-84-1) + butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + peroxide

butanone (78-93-3) → 3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + methyl ethyl ketone peroxide (2780-59-8)

Conditions	Yield
Stage #1: butanone; nitric acid In 2-methylundecane; water; acetic acid at 15 - 18℃; Stage #2: With dihydrogen peroxide In 2-methylundecane; water; acetic acid at 14 - 18℃; for 1h;

3,6,9-triethyl-3,6,9-trimethyl-[1,2,4,5,7,8]hexoxonane (24748-23-0) + 4-tert-Butylstyrene (1746-23-2) → 1-((E)-But-1-enyl)-4-tert-butyl-benzene

Conditions	Yield
With iron(III) trifluoromethanesulfonate In 1,4-dioxane at 80℃; for 12h; Heck Reaction;	81%

Upstream product

• 78-93-3 butanone 
• 7664-93-9 sulfuric acid 
• 7722-84-1 dihydrogen peroxide 
• 107-87-9 2-Pentanone 

Relevant articles and documents

Selective, sensitive, and rapid analysis with lateral-flow assays based on antibody-gated dye-delivery systems: The example of triacetone triperoxide

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METHOD FOR THE PRODUCTION OF TRIMERIC KETONE PEROXIDE SOLUTIONS

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