247936-95-4

Basic information

• Product Name: Tricyclo<5.2.1.0^2.6>deca-3,8-dien
• Synonyms: Tricyclo<5.2.1.0^2.6>deca-3,8-dien
• CAS NO: 247936-95-4
• Molecular Weight: 132.205
• Mol File: 247936-95-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Tricyclo<5.2.1.0^2.6>deca-3,8-dien(CAS DataBase Reference)
• NIST Chemistry Reference: Tricyclo<5.2.1.0^2.6>deca-3,8-dien(247936-95-4)
• EPA Substance Registry System: Tricyclo<5.2.1.0^2.6>deca-3,8-dien(247936-95-4)

Safety Data

• Hazardous Substances Data: 247936-95-4(Hazardous Substances Data)

Upstream product

• 66486-70-2 anti-Tricyclo<4.2.1.1^2,5>deca-3,7-dien 
• 612-09-9 anti-cis-<2+2>-Dicyclopentadien 
• 497-20-1 fulvene 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 110793-50-5 exo-6-hydroxy-exo-4-exo-10-dioxapentacyclo(6.3.1.0.^{2,7_0.3,5₀9,11})dodecane 
• 92892-69-8 exo-6-hydroxy-exo-4-oxatetracyclo(6.2.1.0.^2,70^3,5)-undec-9-ene 
• 123930-79-0 (1R,3aS,4R,7S,7aR)-3a,4,7,7atetrahydro-1H-4,7-methanoinden-1-ol 
• 542-92-7 cyclopenta-1,3-diene 
• 4168-48-3 (1R,2S,7S,8S)-4,10-dioxapentacyclo[6.3.1.0^2,7.0^3,5.0^9,11]dodecane 
• 2825-83-4 (3aR,4R,7S,7aS)-octahydro-1H-4,7-methanoindene 
• 77-73-6 exo-tricyclo[5.2.1.0^2,6]deca-3,8-diene 
• 37005-79-1 [(cyclopent-3-en-1-yloxy)methyl]benzene 
• 14320-38-8 cyclopent-3-enol 

Relevant articles and documents

Does Cycloaddition between Pentafulvene and Cyclopentadiene Take Place?

Reaction of a 1:1 mixture of cyclopentadiene (CPD) and pentafulvene (1a) at 20 deg C gives a complex mixture.The low-molecular-weight part mainly consists of pure and mixed dimers (ca. 73percent) besides corresponding trimers (ca. 20percent) and some corresponding oligomers according to GC/MS investigations (Fig.1).The 3 predominant 'mixed dimers'between CPD and 1a have been separated, and structures 4-6 (Scheme 3) are assigned according to 400- and 600-MHz 1H-NMR investigations.These results show that HOMO(CPD)-LUMO(fulvene) interactions are important in pentafulvene cycloadditions.Dimer 6 results from cycloaddition followed by -H shifts.