24825-01-2

Basic information

• Product Name: Naphth[1,2-b]oxirene, 1a,2,3,7b-tetrahydro-, (1aR,7bS)-
• CAS NO: 24825-01-2
• Molecular Formula: C10H10O
• Molecular Weight: 146.189
• Mol File: 24825-01-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Naphth[1,2-b]oxirene, 1a,2,3,7b-tetrahydro-, (1aR,7bS)-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphth[1,2-b]oxirene, 1a,2,3,7b-tetrahydro-, (1aR,7bS)-(24825-01-2)
• EPA Substance Registry System: Naphth[1,2-b]oxirene, 1a,2,3,7b-tetrahydro-, (1aR,7bS)-(24825-01-2)

Safety Data

• Hazardous Substances Data: 24825-01-2(Hazardous Substances Data)

Upstream product

• 447-53-0 1,2-Dihydronaphthalene 
• 2461-34-9 1a,2,3,7b-tetrahydronaphtho[1,2-b]oxirene 
• 100-42-5 styrene 
• 65437-23-2 d-menthyl diazoacetate 
• 22071-15-4 ketoprofen 
• 5104-49-4 fluorobiprofen 
• 29679-58-1 Fenoprofen 
• 15687-27-1 ibuprofen 
• 492-37-5 hydratropic acid 
• 65-85-0 benzoic acid 
• 2900-27-8 2-(tert-butoxycarbonylamino)-2-phenylacetic acid 
• 90-27-7 2-Phenylbutyric acid 
• 2461-34-9 1,2-epoxy-3,4-dihydronaphthalene 

Downstream Products

• 57496-61-4 (1R,2R)-trans-1,2-dihydroxy-1,2,3,4-tetrahydronaphthalene 
• 766537-21-7 (+)-(1R,2R)-trans-1-(4-chloro-3-methoxyphenyl)-N-(2,2-dimethoxyethyl)-1,2,3,4-tetrahydro-N-methyl-2-naphthaleneamine oxalate salt 
• 17180-88-0 (-)-(1S,2R)-naphthalene 1,2-oxide 
• 17180-88-0 (1R,2S)-(+)-naphthalene 1,2-oxide 

Relevant articles and documents

Peroxygenase-Catalysed Epoxidation of Styrene Derivatives in Neat Reaction Media

Biocatalytic oxyfunctionalisation reactions are traditionally conducted in aqueous media limiting their production yield. Here we report the application of a peroxygenase in neat reaction conditions reaching product concentrations of up to 360 mM.

Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation

The synthesis of the first mesoporous silica (150 A) anchored carbohydrate-derived chiral ketone is described. This new heterogeneous catalyst has been shown to be effective in the asymmetric epoxidation of olefins by oxone. The heterogeneous ketone catalyst has comparable activity to that of its homogeneous counterpart and returned enantioselectivities up to 90% e.e.

Photo-controlled Lewis acidity: Chiral (ON)Ru-salen catalyzed hetero Diels-Alder reaction and kinetic resolution of racemic epoxides

(ON+)(Salen)ruthenium(II) complex 1 serves as a chiral Lewis acid catalyst for asymmetric hetero Diels-Alder reaction and for kinetic resolution of racemic epoxides when the reactions were carried out under sunlight coming through windows or incandescent light.