24863-70-5Relevant articles and documents
A new synthesis of methyl 3-oxo-2-pentyl-1-cyclopentene-1-acetate
Crawford,Rautenstrauch,Uijttewaal
, p. 1127 - 1128 (2007/10/03)
The 92:8 equilibrium mixture of (±)-trans-methyl dihydrojasmonate (1) and its cis-isomer is transformed in 63% overall yield into the title compound 4 by epoxidation of the derived enol acetate 2 with peracetic acid/Na2CO3 in toluene and heating the resulting α-acetoxy epoxide 3 in MeOH in the presence of catalytic amounts of methanesulfonic acid.
ELECTROREDUCTIVE INTRAMOLECULAR COUPLING OF γ- AND δ-CYANOKETONES
Shono, Tatsuya,Kise, Naoki
, p. 1303 - 1306 (2007/10/02)
Electroreduction of γ- and δ-cyanoketones in i-PrOH gave cyclized products α-hydroxyketones and their dehydroxylated ketones, and this reaction was applied to the synthesis of dihydrojasmone, methyl dihydrojasmonate, and Rosaprostol.