24865-83-6Relevant articles and documents
A new preparation of cis-N-sulfonylaziridines from N-sulfonylaldimines using trimethylsilyldiazomethane
Hori,Aoyama,Shioiri
, p. 9455 - 9458 (2000)
Trimethylsilyldiazomethane smoothly reacts with N-sulfonylaldimines to give 2-substituted N-sulfonyl-3-trimethylsilylaziridines in good yields with high cis selectivity. (C) 2000 Elsevier Science Ltd.
Methyltrioxorhenium/urea hydrogen peroxide catalyzed oxidation of N-sulfinyl imines: A mild and highly efficient access to N-sulfonyl aldimines, ketimines and α-ketiminoesters
Tan, Yu,Ma, Ru-Lin,Lin, Hua,Sun, Xing-Wen
supporting information, (2020/11/25)
A mild and highly efficient access to N-sulfonyl imines through the oxidation of corresponding N-tert-butylsulfinyl imines and N-p-tosyl-sulfinyl imines with UHP in the presence of catalytic amount MTO was developed. Under mild reaction conditions, this h
Catalyst-controlled regiodivergent ring-opening C(sp3)-Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis
Takeda, Youhei,Shibuta, Kaoru,Aoki, Shohei,Tohnai, Norimitsu,Minakata, Satoshi
, p. 8642 - 8647 (2019/10/02)
A catalyst-controlled regiodivergent and stereospecific ring-opening C(sp3)-Si cross-coupling of 2-arylaziridines with silylborane enabled by synergistic Pd/Cu dual catalysis has been developed. Just by selecting a suitable combination of catalysts, the regioselectivity of the coupling is completely switched to efficiently provide two regioisomers of β-silylamines (i.e., β-silyl-α-phenethylamines and β-silyl-β-phenethylamines) in good to high yields. Furthermore, a slight modification of the reaction conditions caused a drastic change in reaction pathways, leading to a tandem reaction to produce another regioisomer of silylamine (i.e., α-silyl-β-phenethylamines) in an efficient and selective manner.