2489-03-4Relevant articles and documents
On-surface synthesis of graphyne nanowires through stepwise reactions
Yu, Xin,Cai, Liangliang,Bao, Meiling,Sun, Qiang,Ma, Honghong,Yuan, Chunxue,Xu, Wei
, p. 1685 - 1688 (2020)
From an interplay of high-resolution UHV-STM imaging and DFT calculations, we have achieved on-surface synthesis of graphyne nanowires through stepwise reactions involving two different types of dehalogenative homocoupling reactions (i.e., C(sp3/sup
Base-Promoted Synthesis of 2-Aryl Quinazolines from 2-Aminobenzylamines in Water
Chatterjee, Tanmay,Kim, Dong In,Cho, Eun Jin
, p. 7423 - 7430 (2018/07/29)
A transition-metal-free procedure for the synthesis of a highly valuable class of heteroaromatics, quinazolines, was developed by using easily available 2-aminobenzylamines and α,α,α-trihalotoluenes. The transformation proceeded smoothly in the presence of only sodium hydroxide and molecular oxygen in water at 100 °C, furnishing a variety of 2-aryl quinazolines. The crystallization process of the crude reaction mixture for the purification of the solid products circumvents huge solvent-consuming workup and column chromatographic techniques, which make the overall process more sustainable and economical.
Catalytic halodefluorination of aliphatic carbon-fluorine bonds
Goh, Kelvin K.K.,Sinha, Arup,Fraser, Craig,Young, Rowan D.
, p. 42708 - 42712 (2016/05/19)
A variety of halosilanes, in conjunction with aluminum catalysts, convert fluorocarbons into higher halocarbons. Bromination and iodination of fluorocarbons are more effective than chlorination in terms of yield and activity. The mechanism for the reaction is investigated utilizing experimental and computational evidence and preliminary results suggest an alternate mechanism to that reported for the related hydrodefluorination reaction.