24896-50-2

Basic information

• Product Name: 5-phenyl-1,2,3,4-tetrahydrobenzo[a]phenanthridine
• Synonyms: 5-phenyl-1,2,3,4-tetrahydrobenzo[a]phenanthridine
• CAS NO: 24896-50-2
• Molecular Weight: 309.411
• Mol File: 24896-50-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-phenyl-1,2,3,4-tetrahydrobenzo[a]phenanthridine(CAS DataBase Reference)
• NIST Chemistry Reference: 5-phenyl-1,2,3,4-tetrahydrobenzo[a]phenanthridine(24896-50-2)
• EPA Substance Registry System: 5-phenyl-1,2,3,4-tetrahydrobenzo[a]phenanthridine(24896-50-2)

Safety Data

• Hazardous Substances Data: 24896-50-2(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 100-52-7 benzaldehyde 
• 91-59-8 naphthalen-2-ylamine 

Relevant articles and documents

Metal-Free Synthesis of Benzo[a]phenanthridines from Aromatic Aldehydes, Cyclohexanones, and Aromatic Amines

A three-component synthesis of benzo[α]phenanthridines from aromatic aldehydes, cyclohexanones, and aromatic amines has been developed, which is mediated by KI/DMSO/camphorsulfonic acid to afford a variety of functionalized benzo[α]phenanthridines in satisfactory yields. The present strategy provides a biaryl motif ortho to the nitrogen atom which has the potential to be used as ligand by further modification. With the advantages of readily available starting materials, transition-metal-free conditions, gram-scale synthesis, and broad substrate scope, this three-component protocol provides an efficient approach for the preparation of diverse benzo[α]phenanthridines.