24949-41-5Relevant articles and documents
A NOVEL ZIRCONIUM-CATALYZED HYDROALUMINATION OF OLEFINS
Negishi, Ei-ichi,Yoshida, Tadao
, p. 1501 - 1504 (2007/10/02)
Sterically hindered trialkylalanes, such as triisobutylalane, react with olefins at or below room temperature under the influence of a catalytic amount of Cl2ZrCp2 to effect hydroalumination of the olefins.The reaction can tolerate certain hetero-functional groups, such as OH, SPh and Br, which tend to interfere with previously reported hydroalumination procedures.