24978-42-5

Basic information

• Product Name: (E,E)-N¹,N²-bis(4-methoxyphenyl)ethane-1,2-diimine
• Synonyms: (E,E)-N¹,N²-bis(4-methoxyphenyl)ethane-1,2-diimine
• CAS NO: 24978-42-5
• Molecular Weight: 268.315
• Mol File: 24978-42-5.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: (E,E)-N¹,N²-bis(4-methoxyphenyl)ethane-1,2-diimine(CAS DataBase Reference)
• NIST Chemistry Reference: (E,E)-N¹,N²-bis(4-methoxyphenyl)ethane-1,2-diimine(24978-42-5)
• EPA Substance Registry System: (E,E)-N¹,N²-bis(4-methoxyphenyl)ethane-1,2-diimine(24978-42-5)

Safety Data

• Hazardous Substances Data: 24978-42-5(Hazardous Substances Data)

Upstream product

• 131543-46-9 Glyoxal 
• 104-94-9 4-methoxy-aniline 
• 110-91-8 morpholine 
• 536-75-4 4-Ethylpyridine 
• 100-61-8 N-methylaniline 
• 2206-27-1 dimethylsulfoxide-d6 
• 113872-71-2 PdCl₂(C₆H₄OMe-p)NCHCHN(C₆H₄OMe-p) 
• 113872-72-3 PtCl₂(C₆H₄OMe-p)NCHCHN(C₆H₄OMe-p) 
• 124870-70-8 1-(4-methoxyphenyl)-3,3-dimethyl-4-oxoazetidine-2-carbaldehyde 
• 133505-04-1 cis-4-formyl-1-(p-methoxyphenyl)-3-phenoxyazetidin-2-one 
• 162900-36-9 [(Z)-4-Methoxy-phenylimino]-acetaldehyde 
• 1122-58-3 dmap 
• 626-61-9 4-Chloropyridine 
• 110-86-1 pyridine 

Downstream Products

• 84312-62-9 1,4-Bis-(4-methoxy-phenyl)-6-phenyl-1,4,4a,7a-tetrahydro-pyrrolo[3,4-b]pyrazine-5,7-dione 
• 133504-99-1 1-((2S,3S)-1-(4-Methoxy-phenyl)-2-{[(E)-4-methoxy-phenylimino]-methyl}-4-oxo-azetidin-3-yl)-pyrrole-2,5-dione 
• 128571-93-7 cis-1-(p-methoxyphenyl)-3-ethyl-4-formyl-2-azetidinone 
• 133504-94-6 (3S,4S)-3-Ethyl-1-(4-methoxy-phenyl)-4-{[(E)-4-methoxy-phenylimino]-methyl}-azetidin-2-one 
• 84289-19-0 1-(4-methoxyphenyl)-2,3-diphenyl-1H-pyrrole 
• 84289-12-3 1-(4-Methoxy-phenyl)-2-{[(E)-4-methoxy-phenylimino]-methyl}-4,5-diphenyl-1,2-dihydro-pyrrol-3-one 
• 183066-64-0 (+)-cis-(1-p-methoxyphenyl)-4-formyl-3-[(S)-4-phenyl-2-oxooxazolidin-3-yl]-2-azetidinone 
• 22359-32-6 2-chloro-3-(4-methoxyphenyl)amino-1,4-naphthoquinone 
• 4640-41-9 2,3-dichloro-5,6-dicyanohydroquinone 
• 170209-09-3 (1R,2R)-1,2-N,N'-bis(4-methoxyphenylamino)-1,2-diphenylethane 

Relevant articles and documents

Copper complexes of 1,4-diazabutadiene ligands: Tuning of metal oxidation state and, application in catalytic C-C and C-N bond formation

Reaction of 1,4-diazabutadiene (p-RC6H4N = C(H)(H)C = NC6H4R-p; R = OCH3, CH3, H and Cl; abbreviated as L-R) with CuCl2·2H2O in methanol at ambient temperature (25 °C) affords a group of doubly chloro-bridged dicopper complexes of type [{CuI(L-R)Cl}2], designated as 1-R. Similar reaction carried out in acetonitrile furnishes a family of doubly chloro-bridged dicopper complexes of type [{CuII(L-R)Cl2}2], designated as 2-R. Molecular structures of 1-OCH3 and 2-OCH3 have been determined by X-ray crystallography. While copper(I) is having a nearly tetrahedral N2Cl2 coordination sphere in 1-OCH3, the N2Cl3 coordination sphere around copper(II) is distorted square pyramidal in nature in 2-OCH3. Isolated 2-R complexes, on dissolution in methanol, are found to undergo facile reduction of the metal center to generate the corresponding 1-R complexes. The 1-R and 2-R complexes show intense absorptions in the visible and ultraviolet regions. Cyclic voltammetry on the 1-R and 2-R complexes shows both metal-centered and ligand centered redox responses. The 1-R complexes are found to efficiently catalyze C-N cross-coupling reactions between arylboronic acids and aryl amines; while the 2-R complexes display notable catalytic efficiency for nitroaldol reactions.

The formation of dinuclear trichloro-bridged and mononuclear ruthenium complexes from the reactions of dichlorotris(p-tolylphosphine)ruthenium(II) with diazabutadiene ligands

Ru(II) complexes with diazabutadiene (R-DAB) ligands have been prepared. The reaction of RuCl3·nH2O with P(p-tolyl)3 gave a [RuCl2{P(p-tolyl)3}] precursor, whose reactions with R-DAB in toluene gave d

A silver complex of N,N′-disubstituted cyclic thiourea as an anti-inflammatory inhibitor of IκB kinase

A silver complex of N,N′-disubstituted cyclic thiourea inhibits inflammatory cytokine-stimulated NF-κB activity via IκB kinase inactivation. The Royal Society of Chemistry 2013.