2500-83-6

Basic information

• Product Name: TRICYCLODECENYL ACETATE
• Synonyms: 3A,4,5,6,7,7A-HEXAHYDRO-4,7-METHANO-1(3)H-INDEN-6-YL ACETATE;JASMACYCLENE;CYCLACET;3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-5-ylacetate;4,7-Methano-1H-inden-5-ol,3a,4,5,6,7,7a-hexahydro-,acetate;7-methano-1h-inden-5-ol,3a,4,5,6,7,7a-hexahydro-acetate;Tricyclo[5.2.1.02,6]dec-3-en-9-ylacetate;VERDYL ACETATE
• CAS NO: 2500-83-6
• Molecular Formula: C₁₂H₁₆O₂
• Molecular Weight: 192.25
• EINECS: 219-700-4
• Mol File: 2500-83-6.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 258.4 °C at 760 mmHg
• Flash Point: 101.8 °C
• Appearance: Clear to amber liquid
• Density: 1.12 g/cm³
• Vapor Pressure: 0.0137mmHg at 25°C
• Refractive Index: 1.536
• CAS DataBase Reference: TRICYCLODECENYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRICYCLODECENYL ACETATE(2500-83-6)
• EPA Substance Registry System: TRICYCLODECENYL ACETATE(2500-83-6)

Safety Data

• Hazardous Substances Data: 2500-83-6(Hazardous Substances Data)

Usage

Chemical Properties

TRICYCLODECENYL ACETATE is a colorless liquid with a herbal, fresh, woody odor. It consists of a mixture of isomers that is obtained by addition of acetic acid to dicyclopentadiene in the presence of an acid catalyst. It is used for perfuming soaps, detergents, and air fresheners.

Trade name

Cyclacet? (IFF), Jasmacyclene (Givaudan), Verdyl acetate (Kalp- Sutra), Verdyl acetate (Yinghai).

InChI:InChI=1/C12H16O2/c1-7(13)14-12-6-8-5-11(12)10-4-2-3-9(8)10/h2,4,8-12H,3,5-6H2,1H3

Upstream product

• 108-05-4 vinyl acetate 
• 933-60-8 exo-dicyclopentadiene 
• 1755-01-7 endo-Dicyclopentadien 
• 93818-38-3 (1RS,2RS,6RS,7RS,8SR)-tricyclo[5.2.1.0^2,6]dec-4-en-8-yl 4-nitrobenzoate 
• 108-24-7 acetic anhydride 
• 77-73-6 exo-tricyclo[5.2.1.0^2,6]deca-3,8-diene 
• 13080-96-1 methylaceto acetate 
• 133-21-1 (1RS,2RS,6RS,7RS,8SR)-tricyclo[5.2.1.0^2,6]dec-4-en-8-ol 
• 64-19-7 acetic acid 
• 77-73-6 bi(cyclopentadiene) 

Downstream Products

• 501929-86-8 (1S,2S,6S,7S,8R)-tricyclo[5.2.1.0^2,6]dec-4-en-8-ol 
• 501929-84-6 (1R,2R,6R,7R,8S)-tricyclo[5.2.1.0^2,6]dec-4-en-8-ol 

Relevant articles and documents

Stereoselective exo-addition to norbornenes of acetic acid generated from vinyl acetate in the presence of rhodium complexes

Rhodium complexes catalyzed decomposition of vinyl acetate with liberation of acetic acid and subsequent stereoselective exo-addition of the latter to norbornene and its derivatives under mild conditions.

Synthesis of esters from cage-like unsaturated hydrocarbons, carboxylic acid anhydrides, and water

A convenient method for the preparation of esters was developed on the basis of reaction of cage-like polycyclic olefins with carboxylic acid anhydrides and water. Mixed anhydrides were found to give rise to the corresponding low-molecular acid esters. Among the obtained esters, acetates possess a pleasant odor, and they can be used as components of synthetic fragrant substances.

Production of "dicylate" perfume

The method for producing "dicylate" - tricyclo[5,2,1,02,6]dec-3-enyl-8(9)-acetate -from acetic acid and tricyclo[5,2,1,02,6]deca-3,8-diene has been improved. The reaction is carried out at a temperature of 130-170°C and spontaneous pressure, which enables the use of strong acids as catalysts to be discarded.