2523-36-6

Basic information

• Product Name: methyl 9H-fluorene-2-carboxylate
• CAS NO: 2523-36-6
• Molecular Formula: C₁₅H₁₂O₂
• Molecular Weight: 224.2546
• Mol File: 2523-36-6.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 380.6°C at 760 mmHg
• Flash Point: 183.4°C
• Density: 1.204g/cm³
• Vapor Pressure: 5.39E-06mmHg at 25°C
• Refractive Index: 1.621
• CAS DataBase Reference: methyl 9H-fluorene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 9H-fluorene-2-carboxylate(2523-36-6)
• EPA Substance Registry System: methyl 9H-fluorene-2-carboxylate(2523-36-6)

Safety Data

• Hazardous Substances Data: 2523-36-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 1133-80-8 2-bromo-9H-fluorene 
• 18982-54-2 o-bromobenzyl alcohol 
• 79-37-8 oxalyl dichloride 
• 86-73-7 9H-fluorene 
• 89900-97-0 methyl 2'-bromo-[1,1'-biphenyl]-4-carboxylate 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 99768-12-4 4-methoxycarbonylphenylboronic acid 
• 615-43-0 2-iodophenylamine 
• 5737-79-1 methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate 
• 74-95-3 1,1-dibromomethane 
• 84966-00-7 methyl 9,9-bis(ethylthio)fluorene-2-carboxylate 
• 84966-03-0 methyl 9-(ethylthio)fluorene-2-carboxylate 

Relevant articles and documents

PROTEIN-MACROMOLECULE CONJUGATES AND METHODS OF USE THEREOF

The present disclosure provides protein-macromolecule conjugates, releasable linkers, and macromolecules, as defined herein. The disclosed conjugates provide unique properties that are based at least upon the properties of linker and number of linker-Macromolecule moieties. Also provided herein are a method of synthesis and use of conjugates in treating diseases and disorders.

Phosphite-catalyzed alkoxycarbonylation of aryl diazonium salts

In this communication, an interesting phosphite-catalyzed alkoxycarbonylation of aryl diazonium salts has been reported. At room temperature and under CO pressure, moderate to good yields of the desired esters can be produced in the absence of bases or an

Palladium-Catalyzed Formal [4 + 1] Annulation via Metal Carbene Migratory Insertion and C(sp2)-H Bond Functionalization

A highly efficient and operationally simple palladium-catalyzed formal [4 + 1] annulation reaction has been developed. The reaction is featured by the formation of two different C-C bonds on a carbenic center. It represents a concise method for the synthesis of a wide range of polycyclic aromatic hydrocarbons (PAHs) and 1H-indenes with easily available (trimethylsilyl)diazomethane as the carbene source. Metal carbene migratory insertion and C(sp2)-H bond activation are proposed as the key steps in this transformation. The reaction further demonstrates the versatility of the carbene-based coupling in combination with various transition-metal-catalyzed transformations.