25274-05-9Relevant articles and documents
Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic β-ketoesters
Mohr, Justin T.,Behenna, Douglas C.,Harned, Andrew M.,Stoltz, Brian M.
, p. 6924 - 6927 (2007/10/03)
(Chemical Equation Presented) Stereochemical alchemy! Racemic allyl β-ketoesters allow the regiocontrolled formation of enolates, where the same catalyst is intimately involved in both the stereoablative (C-C bond-breaking) and stereoselective (C-C bond-f