25362-01-0

Basic information

• Product Name: Phosphonic acid, [(1Z)-2-phenylethenyl]-, diethyl ester
• CAS NO: 25362-01-0
• Molecular Formula: C12H17O3P
• Molecular Weight: 240.239
• Mol File: 25362-01-0.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [(1Z)-2-phenylethenyl]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [(1Z)-2-phenylethenyl]-, diethyl ester(25362-01-0)
• EPA Substance Registry System: Phosphonic acid, [(1Z)-2-phenylethenyl]-, diethyl ester(25362-01-0)

Safety Data

• Hazardous Substances Data: 25362-01-0(Hazardous Substances Data)

Upstream product

• 103-64-0 bromostyrene 
• 122-52-1 triethyl phosphite 
• 42599-24-6 E-styryl iodide 
• 3084-40-0 diethyl (1-hydroxymethyl)phosphonate 
• 7436-90-0 2,2-dibromostyrene 
• 762-04-9 phosphonic acid diethyl ester 
• 1660-94-2 Tetraethyl methylenediphosphonate 
• 100-52-7 benzaldehyde 
• 20408-33-7 diethyl (E)-(2-phenylethenyl)phosphonate 
• 169230-07-3 diethyl (Z)-2-iodovinylphosphonate 
• 98-80-6 phenylboronic acid 
• 100-39-0 benzyl bromide 
• 4631-50-9 diethyl trimethylsilyloxymethylphosphonate 
• 106938-62-9 (diethoxyphosphinyl)methyl trifluoromethanesulfonate 

Downstream Products

• 157690-40-9 ((Z)-2-Phenyl-dec-1-enyl)-phosphonic acid diethyl ester 
• 157690-43-2 ((E)-2-Phenyl-2-p-tolyl-vinyl)-phosphonic acid diethyl ester 
• 480424-06-4 diethyl (E)-1-bromo-2-phenylethenylphosphonate 
• 480424-04-2 diethyl (Z)-1-bromo-2-phenylethenylphosphonate 
• 34157-89-6 (Z)-styrylphosphonic acid 
• 261167-70-8 (2S,3S)-(3-amino-4-hydroxy-3-methyl-2-phenylbutyl)phosphonic acid 
• 618893-53-1 ethyl (2R,3R)-2-[(tert-butoxycarbonyl)amino]-4-(diethoxyphosphoryl)-3-phenylbutanoate 
• 182207-52-9 (2R,4S,5R)-5-[(tert-butoxycarbonyl)amino]-2-ethoxy-4-phenyl-2-oxo-1,2-oxaphosphorinane 
• 618892-95-8 ethyl (2R,3R)-2-amino-3-phenyl-4-(diethoxyphosphoryl)butanoate 
• 618893-45-1 ethyl (2R,3S)-2-[(tert-butoxycarbonyl)amino]-4-(diethoxyphosphoryl)-3-phenylbutanoate 
• 182207-43-8 ethyl (2R,3S)-2-amino-3-phenyl-4-(diethoxyphosphoryl)butanoate 
• 261167-62-8 (2S,5R,1'R)-2-[2'-(diethoxyphosphoryl)-1'-phenylethyl]-3,6-diethoxy-2,5-dihydro-5-isopropyl-2-methylpyrazine 

Relevant articles and documents

cis-vinylphosphonates and 1,3-butadienylphosphonates by zirconation of 1-alkynylphosphonates

(equation presented) Addition of "zirconocene" to 1-alkynylphosphonates gives three-membered zirconacylces that can be hydrolyzed to cis-vinylphosphonates or further reacted with alkynes/hydrolysis to give substituted (Z,E)- and (E,E)-1,3-butadienylphosph

Inverting External Asymmetric Induction via Selective Energy Transfer Catalysis: A Strategy to β-Chiral Phosphonate Antipodes

Enantiodivergent, catalytic reduction of activated alkenes relays stereochemical information encoded in the antipodal chiral catalysts to the pro-chiral substrate. Although powerful, the strategy remains vulnerable to costs and availability of sourcing bo

Nickel(II)-magnesium-catalyzed cross-coupling of 1,1-dibromo-1-alkenes with diphenylphosphine oxide: One-pot synthesis of (E)-1-alkenylphosphine oxides or bisphosphine oxides

A novel nickel(II)-magnesium-mediated cross-coupling of diphenylphosphine oxide with a variety of 1,1-dibromo-1-alkenes has been developed, which provides a powerful and general methodology for the stereoselective synthesis of various (E)-1-alkenylphosphine oxides or bisphosphine oxides, with operational simplicity of the procedure, good to high yields and broad substrate applicability. Mechanistic studies reveal that the reaction might involve a Hirao reduction, cross-coupling and Michael addition. Copyright

Copper-mediated selective cross-coupling of 1,1-dibromo-1-alkenes and heteronucleophiles: Development of general routes to heterosubstituted alkynes and alkenes

Efficient and general procedures for the cross-coupling of 1,1-dibromoalkenes and N-, O-, and P-nucleophiles are reported. Fine-tuning of the reaction conditions allows for either site-selective, double, or alkynylative cross-coupling, therefore providing