25626-99-7

Basic information

• Product Name: Dimethyl-N-m-tolyl-phosphoramidat
• CAS NO: 25626-99-7
• Molecular Weight: 215.189
• Mol File: 25626-99-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Dimethyl-N-m-tolyl-phosphoramidat(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl-N-m-tolyl-phosphoramidat(25626-99-7)
• EPA Substance Registry System: Dimethyl-N-m-tolyl-phosphoramidat(25626-99-7)

Safety Data

• Hazardous Substances Data: 25626-99-7(Hazardous Substances Data)

Upstream product

• 108-44-1 1-amino-3-methylbenzene 
• 7006-89-5 m-Tolyl-imidophosphorsaeure-trimethylester 
• 7006-96-4 Methyl-m-tolyl-amidophosphorsaeure-dimethylester 
• 813-77-4 Dimethyl chlorophosphate 

Relevant articles and documents

Anilinolysis of dimethyl isothiocyanophosphate in acetonitrile

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Phosphoric Amides. 5. Acid-Catalyzed Hydrolysis of Dimethyl N-(Alkylphenyl)phosphoramidates

Studies of the acid-catalyzed hydrolysis of dimethyl N-(alkylphenyl)phosphoramidates demonstrate that the LFER between observed rates and basicities of the leaving amines is different for meta/para- and for ortho- substituted derivatives (slopes of logobsd vs. pKa are 0.4 and 0.9, respectively).Since the ΔS(excit) values and KSIE determined are approximately constant irrespective of the position of an alkyl group, the observed change in the slope of the rate/basicity plot is discussed in terms of the steric effects on solvation rather than as an indication of the change in reaction mechanism.