256392-16-2Relevant articles and documents
In the optically-multiplexed-
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Paragraph 0226-0227, (2020/12/30)
A method for optical super-multiplexing using polyynes to provide enhanced images from stimulated Raman microscopy is disclosed. In some exemplary embodiments, the polyynes are organelle-targeted or spectral barcoded. Imaging can be enhanced by using the polyynes to image whole live cells or specific organelles within live cells. The polyynes can also be used in optical data storage (i.e., encoding) and identification (i.e., decoding) applications.
Novel approach to stabilize unstable molecular wires by simultaneous rotaxane formation - Synthesis of inclusion complexes of oligocarbynes with cyclic host molecules
Sugiyama, Jiro,Tomita, Ikuyoshi
, p. 4651 - 4653 (2008/03/12)
An effective method to stabilize oligocarbynes as a model for polycarbyne by the simultaneous complexation with α-cyclodextrin (α-CD) is described. 1,12-Bis(9-phenanthryl)-1,3,5,7,9,11-dodecahexayne possessing one or two α-CD molecules was prepared by the
Alkyne migration in alkylidene carbenoid species: A new method of polyyne synthesis
Eisler, Sara,Chahal, Navjot,McDonald, Robert,Tykwinski, Rik R.
, p. 2542 - 2550 (2007/10/03)
The synthesis of conjugated polyyne structures via a modification of the Fritsch-Buttenberg-Wiechell (FBW) rearrangement is reported. Our adaptation provides for the 1,2-migration of an alkyne in a carbene/carbenoid intermediate that is conveniently effec