258281-81-1Relevant articles and documents
Oxidative Cleavage of Silyl Ethers by an Oxoammonium Salt
Loman, Jacob J.,Pistritto, Vincent A.,Kelly, Christopher B.,Leadbeater, Nicholas E.
, p. 2372 - 2377 (2016)
A method for the oxidative cleavage of silyl ethers to their corresponding carbonyl species mediated by an oxoammonium salt is described. The resulting aldehydes and ketones are obtained under mild reaction conditions with no observed overoxidation. For robust substrates, heating to reflux temperatures significantly reduces the reaction time.