25832-09-1

Basic information

• Product Name: Benzenebutanoic acid, b-oxo-
• Synonyms: Benzenebutanoic acid, b-oxo-;3-Oxo-4-phenylbutanoic acid
• CAS NO: 25832-09-1
• Molecular Formula: C₁₀H₁₀O₃
• Molecular Weight: 178.1846
• Mol File: 25832-09-1.mol
• Article Data: 10

Chemical Properties

• Melting Point: 70 °C
• Boiling Point: 147 °C(Press: 15 Torr)
• Appearance: /
• Density: 1.212±0.06 g/cm3(Predicted)
• PKA: 3.43±0.32(Predicted)
• CAS DataBase Reference: Benzenebutanoic acid, b-oxo-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenebutanoic acid, b-oxo-(25832-09-1)
• EPA Substance Registry System: Benzenebutanoic acid, b-oxo-(25832-09-1)

Safety Data

• Hazardous Substances Data: 25832-09-1(Hazardous Substances Data)

Upstream product

• 103-82-2 phenylacetic acid 
• 2033-24-1 cycl-isopropylidene malonate 
• 62282-32-0 benzyl 3-oxo-4-phenylbutanoate 
• 103-80-0 phenylacetyl chloride 
• 66696-84-2 5-(1-hydroxy-2-phenylethylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione 
• 124-38-9 carbon dioxide 
• 103-79-7 1-phenyl-acetone 
• 37779-49-0 methyl 3-oxo-4-phenylbutanoate 
• 718-08-1 ethyl 3-oxo-4-phenylbutyrate 
• 18457-04-0 bis(trimethylsilyl) malonate 
• 64-19-7 acetic acid 
• 101-97-3 Ethyl 2-phenylethanoate 

Downstream Products

• 718-08-1 ethyl 3-oxo-4-phenylbutyrate 
• 1266619-51-5 (E)-1,6-diphenylhex-3-en-2-one 
• 38661-84-6 (E)-1,4-diphenylbut-1-en-3-one 
• 38661-86-8 trans-1-phenyl-4-(4-methoxyphenyl)-3-buten-2-one 
• 129083-13-2 trans-1-phenyl-3-hepten-2-one 
• 1266619-50-4 (E)-4-(3-oxo-4-phenylbut-1-enyl)benzonitrile 
• 1524-06-7 1-fluoro-3-phenylpropan-2-one 
• 868054-77-7 2-(2-benzyl-1,3-dioxolan-2-yl)acetic acid 
• 37779-49-0 methyl 3-oxo-4-phenylbutanoate 
• 153525-03-2 (R)-(-)-3-Hydroxy-4-phenylbutanoic acid 
• 1007-32-5 benzyl ethyl ketone 
• 109417-71-2 (E)-1-phenylhex-3-en-2-one 
• 76103-57-6 1-(1-Methyl-pyrrolidin-2-yl)-3-phenyl-propan-2-one 
• 66697-03-8 tert-butyl 4-phenyl-3-oxobutanoate 

Relevant articles and documents

Organocatalyzed asymmetric synthesis of morphans

A general effective organocatalyzed synthesis of enantioenriched morphans with up to 92% ee was developed. The morphan scaffold was constructed in a one-pot tandem asymmetric organocatalyzed Michael addition followed by a domino Robinson annulation/aza-Michael intramolecular reaction sequence from easily available starting materials.

FLUORESCENT LANTHANIDE COMPLEX

A luminescent lanthanide complex using a photo induced electron transfer as the luminescence controlling principle is presented. The complex comprises a substituted 2-quinolinol containing a sensor group and a complex group and lanthanide ion (Ln3+). This complex is allowed to be co-present in a liquid phase with a material to be measured, and the luminescence of said complex is measured.

The reaction of β-ketoacids with allylboronates

Allylboronates react with β-ketoacids to yield tertiary homoallylic β-hydroxycarboxylic acids. The reaction presumably proceeds via a bicyclic transition state. The β-carboxylic substituent enhances the rate of the reaction.