25957-33-9Relevant articles and documents
Comparison of the Reactivity of CF3OX (X = Cl, F) with Some Simple Alkenes
Johri, Kamalesh K.,DesMarteau, Darryl D.
, p. 242 - 250 (2007/10/02)
Reactions of CF3OX (X = Cl, F) with a variety of simple alkenes were carried out to compare the regio- and stereoselectivity of the additions to carbon-carbon double bonds.The observed addition products with CF3OCl are consistent with an electrophilic syn addition.With CF3OF the observed products indicate a different regioselectivity and low stereoselectivity, consistent with a free-radical addition.