25974-59-8Relevant articles and documents
CHROMENES AND CHROMANONES. PART II. THE BIRCH REDUCTION OF PRECOCENE I AND PRECOCENE II
Aniol, Miroslaw,Wawrzenczyk, Czeslaw
, p. 2655 - 2662 (2007/10/02)
The reduction of precocene I (1a), precocene II (1c) and 6-methoxy-2,2-dimethyl-2H-chromene (1b) with sodium or lithium in liquid ammonia was examined.The phenolic compounds and the bicyclic one with partialy reduced benzene ring were obtained as the majo
REGIOSPECIFIC ALKENYLATION OF PHENOLS BY 1,1-DIMETHYLALLENE PROMOTED BY PLATINUM CATALYSTS
Renzi, Augusto De,Panunzi, Achille,Saporito, Antonio,Vitagliano, Aldo
, p. 993 - 996 (2007/10/02)
1,1-Dimethylallene reacts with phenolic substrates in the presence of catalytic amounts of platinum(II) complexes.A regiospecific C-alkenylation takes place, affording o-isopentenylphenols and 2,2-dimethylchromans.Possible reaction mechanisms are also discussed.