260054-47-5Relevant articles and documents
C-H insertion reactions of nucleophilic carbenes
Arduengo III, Anthony J.,Calabrese,Davidson, Fredric,Rasika Dias,Goerlich, Jens R.,Krafezyk, Roland,Marshall, William J.,Tamm, Matthias,Schumtzler, Reinhard
, p. 2348 - 2364 (1999)
Syntheses and characterizations are described for C-H insertion products derived from 1,3-dimesityldihydroimidazol-2-ylidene (1) with acetylene, acetonitrile, methyl phenyl sulfone, and chloroform. In the reaction with acetylene, both acetylenic H-atoms a
Synthesis and NMR study of N-heterocyclic carbenes (NHC) precursors derived from troger's base
Musengimana, Eric,Fatakanwa, Claver
, p. 1489 - 1496 (2014/05/06)
Since the discovery of olefin metathesis reactions, various catalysts have been developed but those based on Ruthenium and N-heterocyclic carbenes (NHC) ligands are particularly more efficient. Herein, we report a synthesis of NHC precursors derived from
High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor
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, (2008/06/13)
The invention provides a method for converting a less active or slower to initiate system to a higher activity system so that at the end of a polymerization the most active species is present in the system. The invention generally relates to a process for