260354-51-6

Basic information

• Product Name: (2S,3R)-2-{(S)-2-Amino-2-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetylamino}-3-(tert-butyl-diphenyl-silanyloxy)-butyric acid methyl ester
• Synonyms: (2S,3R)-2-{(S)-2-Amino-2-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetylamino}-3-(tert-butyl-diphenyl-silanyloxy)-butyric acid methyl ester
• CAS NO: 260354-51-6
• Molecular Weight: 634.845
• Mol File: 260354-51-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3R)-2-{(S)-2-Amino-2-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetylamino}-3-(tert-butyl-diphenyl-silanyloxy)-butyric acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-2-{(S)-2-Amino-2-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetylamino}-3-(tert-butyl-diphenyl-silanyloxy)-butyric acid methyl ester(260354-51-6)
• EPA Substance Registry System: (2S,3R)-2-{(S)-2-Amino-2-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetylamino}-3-(tert-butyl-diphenyl-silanyloxy)-butyric acid methyl ester(260354-51-6)

Safety Data

• Hazardous Substances Data: 260354-51-6(Hazardous Substances Data)

Upstream product

• 260354-46-9 (2S,3R)-2-{(S)-2-Benzylamino-2-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetylamino}-3-(tert-butyl-diphenyl-silanyloxy)-butyric acid methyl ester 
• 260354-47-0 (3R,4S)-1-Benzyl-3-benzyloxy-4-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-azetidin-2-one 
• 260354-35-6 methyl O-t-butyldiphenylsilyl-N-benzyloxycarbonyl-L-threonate 
• 260354-42-5 Acetic acid (2S,3R)-1-benzyl-2-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-4-oxo-azetidin-3-yl ester 
• 260354-45-8 (S)-3-Benzyl-4-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-oxazolidine-2,5-dione 
• 260354-43-6 (3R,4R)-1-Benzyl-3-hydroxy-4-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-azetidin-2-one 
• 260354-34-5 O-(tert-butyldiphenylsilyl)-L-threonine 
• 148205-40-7 O-tert-butyldiphenylsilyl-L-threonine methyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 122517-81-1 (2R,3S)-methyl 2,3-dihydroxy-3-(4-methoxyphenyl)propanoate 
• 3901-07-3 3-(4-methoxy-phenyl)acrylic acid methyl ester 
• 1025887-95-9 Benzyl-[1-[(4S,5S)-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-meth-(E)-ylidene]-amine 

Relevant articles and documents

A strategy for the asymmetric aminohomologation of α,β-dihydroxy aldehydes: Application to the synthesis of the southwest tripeptide segment of echinocandin B

The synthesis of the (2S,3S,4S)-3,4-dihydroxyhomotyrosine amino acid segment, present in echinocandin B, in its activated form ready for peptide coupling is described. The key steps of the approach are the enantioselective AD reaction of 4-methoxycinnamic