26042-64-8

Basic information

• Product Name: Silver hexafluoroantimonate
• Synonyms: silver hexafluoroantimonate(1-);Silverhexafluoroantimonate(V),98%;Silver hexafluoroantimonate 98%;Silverhexafluoroantimonate98%;hexafluoro-, silver, (OC-6-11)-Antimonate;Silver hexafluoroantimonate,99%;Silver hexafluorosilicate ,99%;Silver(I) hexafluoroantimonate(V) 98%
• CAS NO: 26042-64-8
• Molecular Formula: Ag.F6Sb
• Molecular Weight: 343.62
• EINECS: 247-429-1
• Product Categories: Sb (Antimony) Compounds;Ag (Silver) Compounds;Classes of Metal Compounds;Semimetal Compounds;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Gold Catalysis;Salts;Silver AdditivesMetal and Ceramic Science;Silver Salts;SilverCatalysis and Inorganic Chemistry;halometallate salts
• Mol File: 26042-64-8.mol
• Article Data: 6

Chemical Properties

• Appearance: White to pale yellow/Powder/Lump
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Water Solubility: Soluble in water.
• Sensitive: Hygroscopic
• Stability: hygroscopic
• CAS DataBase Reference: Silver hexafluoroantimonate(CAS DataBase Reference)
• NIST Chemistry Reference: Silver hexafluoroantimonate(26042-64-8)
• EPA Substance Registry System: Silver hexafluoroantimonate(26042-64-8)

Safety Data

• Hazard Codes: Xn,N,C
• Statements: 20/22-51/53
• Safety Statements: 61
• RIDADR: UN 3260 8/PG 2
• WGK Germany: 2
• F: 3-8-10
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 26042-64-8(Hazardous Substances Data)

Usage

Description

Silver hexafluoroantimonate is a white to pale yellow crystalline powder, which is a compound of silver, fluorine, and antimony. It is known for its unique chemical properties and is utilized in various applications across different industries.

Uses

Used in Pharmaceutical Industry:
Silver hexafluoroantimonate is used as a catalyst for the synthesis of isocoumarins through benzothiadiazine-fused. This application is significant in the pharmaceutical industry as isocoumarins are important intermediates in the synthesis of various biologically active compounds, including pharmaceuticals.
Used in Chemical Synthesis:
In the field of chemical synthesis, silver hexafluoroantimonate serves as a valuable catalyst due to its unique chemical properties. Its ability to facilitate the synthesis of isocoumarins from benzothiadiazine-fused compounds makes it a useful tool in the development of new chemical entities and materials.
Used in Research and Development:
Silver hexafluoroantimonate is also employed in research and development settings, where its catalytic properties are harnessed to explore new synthetic pathways and develop innovative chemical processes. This contributes to the advancement of scientific knowledge and the creation of novel applications in various industries.

InChI:InChI=1/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6/rAg.F6Sb/c;1-7(2,3,4,5)6/q+1;-1

Upstream product

• 7783-92-8 silver(I) chlorate 
• 17856-92-7 nitronium hexafluoroantimonate 
• 7732-18-5 water 
• 7664-39-3 hydrogen fluoride 
• 7783-70-2 antimony pentafluoride 
• 7787-71-5 bromine trifluoride 
• 7783-56-4 antimony(III) fluoride 
• 7782-41-4 fluorine 
• 623171-37-9 [AgP(C₆H₅)3]⁽¹⁺⁾*SbF₆^(1-)=[AgP(C₆H₅)3](SbF₆) 
• 19379-47-6 BrF₂⁽¹⁺⁾*SbF₆^(1-)=(BrF₂)SbF₆ 
• 35967-89-6 silver tetrafluorobromate 
• 14104-20-2 silver tetrafluoroborate 
• 637348-45-9 silver(I) undecafluorodiantimonate(V) 
• 11113-87-4 silver fluoride 

Downstream Products

• 623171-37-9 [AgP(C₆H₅)3]⁽¹⁺⁾*SbF₆^(1-)=[AgP(C₆H₅)3](SbF₆) 
• 128025-11-6 diphenylphosphino 3-methylbut-2-enoate bis(triphenylphosphine)rhodium(I) hexafluoroantimonate 
• 119861-74-4 {Rh(1,5-cyclooctadiene)(η2-(o-bromophenyl)diphenylphosphine)}SbF6 
• 199659-80-8 Mn(C₂₀H₈N₄(C₆H₄CH₃)4)(C₄H₈O)2⁽¹⁺⁾*SbF₆^(1-)=[Mn(C₂₀H₈N₄(C₆H₄CH₃)4)(C₄H₈O)2]SbF₆ 
• 756524-51-3 [η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt-(trans-1,3-diphenylpropenyl)palladium(1+)*SbF6(1-) 
• 753459-01-7 δ-[(1,4-bis(diphenylphosphino)-1,2,3,4-tetraphenyl-1,3-butadiene)Pt(hexafluoroantimonato)2] 

Relevant articles and documents

The volume-based thermodynamics (VBT) and attempted preparation of an isomeric salt, nitryl chlorate: [NO2][ClO3]

Nitrosyl perchlorate, [NO][ClO4], is a known and stable salt. In this contribution we describe the attempt to synthesize the isomeric compound nitryl chlorate, [NO2][ClO3]. The results are discussed on the basis of volume-based thermodynamics (VBT).

Multinuclear NMR solution studies on complexes of hexakis(pyrazol-1-yl)benzene (hpzb) with Ag(I)

The reaction of the polydentate N-donor ligand hexakis(pyrazol-1-yl)benzene (hpzb) with AgSbF6/PPh3 or AgClO4PPh3 in a 1:1 ratio leads to the complexes [Ag(PPh3)(hpzb)]SbF6 (1) or [Ag(PPh3)(hpzb)]ClO4 (3). When two or three equivalents of the silver derivatives are used the species [Ag(PPh3)2]X are formed in addition to 1 or 3. In the case of SbF6- the remaining Ag+ competes with AgPPh3+ for coordination to hpzb and the derivative [Ag(hpzb)]SbF6 (2) is also obtained, while in the case of ClO4- the insoluble salt AgClO4 is formed. The same reactions performed with hpzb-15N12 confirmed the presence of the N-donor ligand in 1-3. At room temperature a Ag-P dissociation process is observed for all the derivatives containing Ag-PPh3 fragments. Complexes 1-3 show in solution an intramolecular argentotropic shift that makes the six pyrazolyl rings of the hpzb ligand equivalent on the 1H NMR time scale. When the amount of counteranion present in solution is sufficiently high, an intermediate of lower coordination number (stabilized with the anion) is observed for complexes 1 and 3 in the low temperature 31P NMR spectra in addition to the three-coordinated species. This intermediate is more stable in the case of ClO4- due to the higher coordinating ability of this anion.