260547-98-6

Basic information

• Product Name: 4-methylphenyl 1-(methylsulfanyl)-1-propenyl sulfone
• Synonyms: 4-methylphenyl 1-(methylsulfanyl)-1-propenyl sulfone
• CAS NO: 260547-98-6
• Molecular Formula: C11H14O2S2
• Molecular Weight: 242.35766
• Mol File: 260547-98-6.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-methylphenyl 1-(methylsulfanyl)-1-propenyl sulfone(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methylphenyl 1-(methylsulfanyl)-1-propenyl sulfone(260547-98-6)
• EPA Substance Registry System: 4-methylphenyl 1-(methylsulfanyl)-1-propenyl sulfone(260547-98-6)

Safety Data

• Hazardous Substances Data: 260547-98-6(Hazardous Substances Data)

Upstream product

• 94816-47-4 1-(methylthio)-1-propyl p-tolyl sulfone 
• 59662-65-6 methylthiomethyl p-tolyl sulfone 
• 75-07-0 acetaldehyde 
• 99946-81-3 1-chloro-1-(methylthio)-1-propyl p-tolyl sulfone 

Downstream Products

• 219533-77-4 2-Methyl-3-methylsulfanyl-1-phenyl-3-(toluene-4-sulfonyl)-propan-1-one 

Relevant articles and documents

Heterocyclic synthesis by C-C bond formation. Thionium ion-mediated preparation of substituted pyrrolidines and piperidines

Dithioacetal-S,S-dioxides 6 and 7 undergo cyclisation to give pyrrolidines and piperidines upon exposure to Lewis acid. An unexpected tandem cyclisation of 5 to give 10 is described.

A Facile Allylic 1,3-Rearrangement of a Sulfonyl Group and Its Application to a Synthesis of α,β-Unsaturated Ketones

A p-tolylsulfonyl group undergoes a SiO2-catalyzed 1,3-rearrangement in a sulfenylated allylic system and this rearrangement can be utylized in novel and convenient syntheses of α,β-unsaturated ketones 6 using 3-(methylthio)-2-propenyl p-tolyl sulfone (1)