26137-09-7

Basic information

• Product Name: 2-Thiophenemethanol, 3-bromo-a-phenyl-
• CAS NO: 26137-09-7
• Molecular Formula: C11H9BrOS
• Molecular Weight: 269.162
• Mol File: 26137-09-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Thiophenemethanol, 3-bromo-a-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Thiophenemethanol, 3-bromo-a-phenyl-(26137-09-7)
• EPA Substance Registry System: 2-Thiophenemethanol, 3-bromo-a-phenyl-(26137-09-7)

Safety Data

• Hazardous Substances Data: 26137-09-7(Hazardous Substances Data)

Upstream product

• 3140-93-0 2,3-dibromothiophen 
• 100-52-7 benzaldehyde 
• 930-96-1 3-bromo-2-thiophenecarboxaldehyde 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 26137-10-0 (3-bromothiophen-2-yl)(phenyl)methanone 
• 138474-51-8 2-benzyl-3-(α-methoxybenzyl)thiophene 
• 138474-50-7 2-benzyl-3-(α-hydroxybenzyl)thiophene 
• 138474-49-4 2-benzyl-3-thiophenecarbaldehyde 
• 138474-48-3 2-benzyl-3-bromothiophene 

Relevant articles and documents

Palladium(II)-catalyzed Intermolecular Cascade Cyclization of Methylenecyclopropanes with Aromatic Alkynes: Construction of Spirocyclic Compounds Containing Indene and 1,2-Dihydronaphthalene Moieties

A palladium(II)-catalyzed intermolecular cascade cyclization of methylenecyclopropanes with aromatic alkynes is reported in this paper. The reaction involves a migratory insertion of alkyne, an intramolecular Heck-type reaction, and β-H elimination, providing a series of spirocyclic compounds containing indene and 1,2-dihydronaphthalene moieties in moderate to excellent yields upon heating.