261907-79-3

Basic information

• Product Name: Boranediamine, 1-(dimethylphenylsilyl)-N,N,N',N'-tetrakis(1-methylethyl)-
• CAS NO: 261907-79-3
• Molecular Formula: C20H39BN2Si
• Molecular Weight: 346.44
• Mol File: 261907-79-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Boranediamine, 1-(dimethylphenylsilyl)-N,N,N',N'-tetrakis(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Boranediamine, 1-(dimethylphenylsilyl)-N,N,N',N'-tetrakis(1-methylethyl)-(261907-79-3)
• EPA Substance Registry System: Boranediamine, 1-(dimethylphenylsilyl)-N,N,N',N'-tetrakis(1-methylethyl)-(261907-79-3)

Safety Data

• Hazardous Substances Data: 261907-79-3(Hazardous Substances Data)

Upstream product

• 28049-80-1 bis(diisopropylamino)chloroborane 
• 768-33-2 phenyldimethylsilyl chloride 
• 108-18-9 diisopropylamine 
• 3839-31-4 dimethyl(phenyl)silyl lithium 

Downstream Products

• 114431-81-1 3-(dimethyl(phenyl)silyl)methyl butanoate 

Relevant articles and documents

NNB-type tridentate boryl ligands enabling a highly active iridium catalyst for C–H borylation

Boryl ligands play a very important role in catalysis because of their very high electron-donating property. In this paper, NNB-type boryl anions were designed as tridentate ligands to promote aryl C–H borylation. In combination with [IrCl(COD)]2/su

New generation of organosilyl radicals by photochemically induced homolytic cleavage of silicon-boron bonds

Unlike bis(diethylamino)organosilylboranes, bis(diisopropylamino)organosilylboranes, which have UV absorption at longer wavelength than 300 nm, undergo photolysis to afford pairs of an organosilyl radical and a bis(diisopropylamino)boryl radical by homolytic scission of the silicon-boron bonds. Generation of organosilyl radical and organoboryl radical was confirmed by trapping experiments using TEMPO (2,2,6,6-tetramethylpiperidine N-oxyl). The organosilyl radical thus generated induces not only silylation of mono-olefins and silylative cyclization of dienes but also polymerization to afford polymers bearing organosilyl termini. On the other hand, the bis(diisopropylamino)boryl radical generated is not incorporated into the olefin adducts.