261963-22-8

Basic information

• Product Name: (-)-3-oxo-4-[(R)-(phenyl)(phenylmethoxycarbonylamino)acetoxy]butanoic acid methyl ester
• Synonyms: (-)-3-oxo-4-[(R)-(phenyl)(phenylmethoxycarbonylamino)acetoxy]butanoic acid methyl ester
• CAS NO: 261963-22-8
• Molecular Weight: 399.4
• Mol File: 261963-22-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-3-oxo-4-[(R)-(phenyl)(phenylmethoxycarbonylamino)acetoxy]butanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-3-oxo-4-[(R)-(phenyl)(phenylmethoxycarbonylamino)acetoxy]butanoic acid methyl ester(261963-22-8)
• EPA Substance Registry System: (-)-3-oxo-4-[(R)-(phenyl)(phenylmethoxycarbonylamino)acetoxy]butanoic acid methyl ester(261963-22-8)

Safety Data

• Hazardous Substances Data: 261963-22-8(Hazardous Substances Data)

Upstream product

• 32807-28-6 Methyl 4-chloroacetoacetate 

Downstream Products

• 196937-28-7 (-)-2-[(3S,5R)-6-oxo-5-phenylmorpholin-3-yl]acetic acid methyl ester 
• 196937-26-5 2-[(3R,5R)-6-oxo-5-phenylmorpholin-3-yl]acetic acid methyl ester 
• 196937-33-4 (2S)-[(2-hydroxy-(1R)-phenyl)ethylamino]butan-1,4-diol 
• 196937-24-3 (-)-Z-[(6-oxo-5R-phenyl)morpholin-3-yliden]acetic acid methyl ester 

Relevant articles and documents

A general synthesis of enantiopure 1,2-aminoalcohols via chiral morpholinones

Eleven optically active 1,2-aminoalcohols 20a-i and 26b-c were prepared from D-phenylglycine via cyclic imines 7b-i (or enamine 7a). The key step of the strategy is the diastereoselective reduction of chiral oxazinones 7a-i.