263160-71-0

Basic information

• Product Name: 2,6-bis(hydroxymethyl)-4-iodophenol
• Synonyms: 2,6-bis(hydroxymethyl)-4-iodophenol
• CAS NO: 263160-71-0
• Molecular Weight: 280.062
• Mol File: 263160-71-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,6-bis(hydroxymethyl)-4-iodophenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-bis(hydroxymethyl)-4-iodophenol(263160-71-0)
• EPA Substance Registry System: 2,6-bis(hydroxymethyl)-4-iodophenol(263160-71-0)

Safety Data

• Hazardous Substances Data: 263160-71-0(Hazardous Substances Data)

Upstream product

• 2937-59-9 2,6-bis(hydroxymethyl)phenol 
• 107274-63-5 diethyl 2-methoxyisophthalate 
• 1951-38-8 2-methoxyisophthalic acid 

Downstream Products

• 446069-79-0 4-iodo-2,6-bis(trimethylsilyloxymethyl)phenol trimethylsilyl ether 

Relevant articles and documents

Coordination cluster analogues of the high-Spin [Mn19] system with functionalized 2,6-Bis(hydroxymethyl)phenol ligands

A series of 2,6-bis(hydroxymethyl)-4-R-phenol ligands (H3LR; R = H, F, Cl, Br, I, Ph, NH2, NO2, SMe) have either been newly synthesized or the existing syntheses have been significantly improved to investigate ligand-functionalized analogues of the previously published coordination cluster [MnIII12MnII7(μ4-O)8(μ3-N3)8(HLMe)12(MeCN)6]Cl2·10MeOH·MeCN (1) with S = 83/2. The crystal structures and magnetic properties of three such Mn19 clusters, namely, [MnIII12MnII7(μ4-O)8(HLH)12(μ3-Cl)7(μ3-OMe)(MeOH)6]Cl2·16H2O·10MeOH·MeCN (3), [MnIII12MnII7(μ4-O)8(HLI)12(μ3-N3)8(MeOH)6](O2CH)2·16MeOH·10MeCN (4) and [MnIII12MnII7(μ4-O)8(μ3-Cl)7.7(μ3-OMe)0.3(HLSMe)12(MeOH)6]Cl2·27MeOH (5) are reported and compared to those of the parent cluster. When these ligands are functionalized with substituents of moderate electronegativity, it is possible to synthesize Mn19 analogues; however, when such ligands bear highly electron-donating (amino) or -withdrawing (nitro) substituents, the Mn19 analogues are no longer accessible. The Mn19 cluster framework is both magnetically and structurally robust with respect to the electron-donor/acceptor characteristics of the ligand substituent; therefore, the Mn19 system is an excellent platform for peripheral chemical engineering. The robustness of the inorganic {MnIII12MnII7(μ4-O)8} core of Mn19 systems with variously functionalized encapsulating ligands is demonstrated by the invariance of the record S = 83/2 spin state. Chemical modification aimed towards attaching the molecule to various substrates does not interfere with the electronic structure.

Preparation of functionalised aryl alkynes as precursors to extended cyclophanes

The preparation of 2,6-substituted arylhalides and triflates is described. These compounds are suitable precursors for cyclophane formation. (C) 2000 Elsevier Science Ltd.