263237-03-2

Basic information

• Product Name: [Cu(triphenylstibine)(N,N-dimethyl-N'-phenylthiourea)2Cl]
• CAS NO: 263237-03-2
• Molecular Weight: 812.613
• Mol File: 263237-03-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(triphenylstibine)(N,N-dimethyl-N'-phenylthiourea)2Cl](CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(triphenylstibine)(N,N-dimethyl-N'-phenylthiourea)2Cl](263237-03-2)
• EPA Substance Registry System: [Cu(triphenylstibine)(N,N-dimethyl-N'-phenylthiourea)2Cl](263237-03-2)

Safety Data

• Hazardous Substances Data: 263237-03-2(Hazardous Substances Data)

Upstream product

• 21507-21-1 chlorotris(triphenylstibine)copper(I) 
• 705-62-4 N,N-dimethyl-N'-phenylthiourea 

Relevant articles and documents

Synthesis and characterization of mixed-ligand complexes of Cu(I) containing halides, triphenylstibine and triphenylbismuthine, N,N-dimethyl-N′-phenylthiourea (dmptH), N,N-dibutyl-N′-phenylthiourea (dbptH) and 1,3-thiazolidine-2-thione (tzdtH)

The triphenylstibine and bismuthine complexes [Cu(EPh3)(LH)2X] (LH = N,N-dimethyl-N′-phenylthiourea) (dmptH), N,N-dibutyl-N′-phenylthiourea (dbptH) or 1,3-thiazolidine-2-thione (tzdtH); E = Sb or Bi; X = Cl, Br or I have been prepared and characterized on the basis of analytical, IR, electronic (UV-Vis), 1H and 13C NMR, FAB mass and conductivity measurements. In all cases there is a distorted tetrahedral environment around Cu(I) and the ligand (LH) binds through the thione sulphur atom to copper(I). This is confirmed by FTIR spectra of the complexes. The complexes show ν(Cu-Sb) in the range 180-195 cm-1.