26370-28-5Relevant articles and documents
SYNTHESIS OF THE TWO ISOMERS OF THE POTENTIAL SEX PHEROMONE OF THAUMETOPOEA PITYOCAMPA (LEPIDOPTERA, NOTODONTIDAE) AND RELATED MODEL COMPOUNDS
Camps, Francisco,Coll, Jose,Canela, Ramon,Guerrero, Angel,Riba, Magi
, p. 703 - 706 (1981)
The synthesis of the major component of the sex pheromone secretion of the processionary moth, Thaumetopoea pityocampa (Denis and Schiff.) (Lepidoptera, Notodontidae), (Z)-13-hexadecen-11-ynyl acetate (1), the corresponding (E)-isomer (2) and the four structurally related model compounds (Z/E,Z,Z)-5,9,13-hexadecatrienyl acetate (3), (Z/E,Z,Z)-3,7,11-hexadecatrienyl acetate (4), (Z/E,E,Z)-7,9,13-hexadecatrienyl acetate (5) and (Z)-7-hexadecen-5-ynyl acetate (6) is described.
PROCESS FOR PREPARING (E2)-CIS-6,7-EPOXY-2-NONENAL
-
Paragraph 0075-0080, (2020/04/02)
To provide an industrial and economical process for preparing (E2)-cis-6,7-epoxy-2-nonenal.SOLUTION: The present invention provides a process for preparing (E2)-cis-6,7-epoxy-2-nonenal, comprising at least steps of: subjecting (Z3,Z6)-3,6-nonadien-1-ol to oxidation, to form (E2,Z6)-2,6-nonadienal; and epoxidizing the resulting (E2,Z6)-2,6-nonadienal to form (E2)-cis-6,7-epoxy-2-nonenal.SELECTED DRAWING: None
PROCESS FOR PREPARING (E2,Z6)-2,6-NONADIENAL
-
Paragraph 0061-0066, (2020/03/09)
The object of the present invention is to provide an industrial and economical process for preparing (E2,Z6)-2,6-nonadienal of the following formula (4): The present invention provides a process for preparing (E2,Z6)-2,6-nonadienal (4), comprising at least steps of: subjecting (Z3,Z6)-3,6-nonadien-1-ol of the following formula (1): to oxidation with a sulfoxide compound of the following formula (2): [in-line-formulae]CH3(R′)S═O??(2)[/in-line-formulae]in which R1 represents a monovalent hydrocarbon group having from 1 to 12 carbon atoms,in the presence of a sulfur trioxide complex and an amine compound of the following formula (3): [in-line-formulae]N(R2)(R3)(R4)??(3)[/in-line-formulae]in which R2, R3, and R4 each independently represent a monovalent hydrocarbon group having from 1 to 12 carbon atoms, or R3 and R4 may be bonded to each other to form a divalent hydrocarbon group having from 3 to 12 carbon atoms, R3-R4,to form the aforesaid (E2,Z6)-2,6-nonadienal (4).