26452-74-4

Basic information

• Product Name: germane, [(1,1-dimethylethyl)dioxy]triethyl-
• Synonyms: (tert-Butylperoxy)(triethyl)germane
• CAS NO: 26452-74-4
• Molecular Formula: C₁₀H₂₄GeO₂
• Molecular Weight: 248.9364
• Mol File: 26452-74-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 209.646°C at 760 mmHg
• Flash Point: 61.457°C
• Vapor Pressure: 0.29mmHg at 25°C
• CAS DataBase Reference: germane, [(1,1-dimethylethyl)dioxy]triethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: germane, [(1,1-dimethylethyl)dioxy]triethyl-(26452-74-4)
• EPA Substance Registry System: germane, [(1,1-dimethylethyl)dioxy]triethyl-(26452-74-4)

Safety Data

• Hazardous Substances Data: 26452-74-4(Hazardous Substances Data)

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 994-28-5 triethylchlorogermane 
• 1876-22-8 di-tert-butyl diperoxyoxalate 
• 1188-14-3 Triethylgerman 
• 56-23-5 tetrachloromethane 
• 556-91-2 aluminum tri-tert-butoxide 

Relevant articles and documents

Reaction of organoelement hydrides R3EH (E = Si, Ge) with metal tert-butylate (M = Al, Ti)-tert-butyl hydroperoxide oxidative systems

Trialkyl(aryl)silanes and -germanes effectively react with metal (Al, Ti) tert-butylate-tert-butyl-hydroperoxide under mild conditions (room temperature, benzene or tetrachloromethane) mainly by the element-hydrogen bond. The character of the products depends on the nature of the element, the structure of the radical bound to it, and the solvent. The process is radical in nature. It includes the stages of formation of element-centered radicals and their reaction with the oxygen generated by the system. The intermediate organometallic peroxides can also acts as oxidants for the element (Si, Ge)-hydrogen bonds. 2005 Pleiades Publishing, Inc.