264621-78-5

Basic information

• Product Name: but-3-enyl (4S)-3-but-3-enyl-2-oxooxazolidine-4-carboxylate
• Synonyms: but-3-enyl (4S)-3-but-3-enyl-2-oxooxazolidine-4-carboxylate
• CAS NO: 264621-78-5
• Molecular Weight: 239.271
• Mol File: 264621-78-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: but-3-enyl (4S)-3-but-3-enyl-2-oxooxazolidine-4-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: but-3-enyl (4S)-3-but-3-enyl-2-oxooxazolidine-4-carboxylate(264621-78-5)
• EPA Substance Registry System: but-3-enyl (4S)-3-but-3-enyl-2-oxooxazolidine-4-carboxylate(264621-78-5)

Safety Data

• Hazardous Substances Data: 264621-78-5(Hazardous Substances Data)

Upstream product

• 7766-51-0 4-iodobut-1-ene 
• 264621-69-4 ethyl (S)-2-oxooxazolidinine-4-carboxylate 
• 96751-61-0 (S)-4-methoxycarbonyl-oxazolidin-2-one 

Relevant articles and documents

From amino acids to fused chiral pyrrolidines and piperidines via the INOC route

Intramolecular nitrile oxide olefin cycloaddition (INOC) reactions of oximes 1-3 and of 24-27 derived from 1-amino acids have been found to proceed stereoselectively, yielding tricyclic fused pyrrolidines and piperidines. Further manipulation led to chiral hydroxymethyl-substituted fused piperidines 33-35 and to 3-amino-4-(1-hydroxypropyl)-2-mercaptomethyl-N- methylpiperidine (36). The structures and stereochemistries of the fused systems, as well as those of the piperidines, have been established by NMR.