26496-20-8Relevant articles and documents
STUDY OF THE TELOMERIZATION OF ETHYLENE AND 1-HEXENE BY BUTANAL THROUGH COMPARATIVE KINETICS
Orlova, S. V.,Ikonnikov, N. S.,Terent'ev, A. B.
, p. 1222 - 1225 (1990)
The reaction of ethylene and 1-hexene with butanal was studied using tertiary butyl peroxide initiation at 140 deg C and a hydrostatic pressure in the range of 250-450 kg/cm2.Based on calculated values of the rate constant ratios for the addition reaction of the n-C3H7CO radical to ethylene (k0e) and 1-hexene (k0h), we obtained k0e/l0h = 3.7 as the rate constant of the decarbonylation reaction of this radical (kd).The partial chain transfer constants were calculated for the ethylene-butanal system as Cn: C1 = 1.0 +/- 0.16; C2 = 1.0 +/- 0.14; C3 = 0.9 +/- 0.23.The results obtained indicate the nucleophilic character of the n-C3H7CO radical in these reactions.
A new organo-ruthenium substituted tungstotellurate: Synthesis, structural characterization and catalytic properties
Zheng, Da-Ming,Wang, Rui-Qiang,Du, Yu,Hou, Guang-Feng,Wu, Li-Xin,Bi, Li-Hua
, p. 8829 - 8836 (2016/10/11)
Reaction of [RuC6H6Cl2]2 with TeO2 and Na2WO4·2H2O in aqueous solution (pH 4.7) yielded a novel organo-ruthenium supported tungstotellurate polyanion, [Te2W20O70(RuC6H6)2]8- (Ru-1), which is composed of two [RuC6H6]2+ units linked to a [Te2W20O70]12- fragment through Ru-O(W) bonds resulting in an assembly with idealized C2h symmetry. Furthermore, the polyanion Ru-1 was anchored on 3-aminopropyltriethoxysilane (apts)-modified SBA-15 to prepare new catalysts (SBA-15-apts-Ru-1) containing different amounts of Ru-1, which were characterized using powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), N2-adsorption measurement and Fourier transform infrared reflectance (FT-IR) spectroscopy. Finally, the catalytic activity of SBA-15-apts-Ru-1 was evaluated for the aerobic oxidation of n-tetradecane using air as the oxidant in the absence of any additives or solvents. In addition, the optimum catalytic reaction conditions were also determined.
Vinylic Organoboranes. 6. A General Synthesis of (E)-Disubstituted Alkenes or Ketones via the (E)-(1-Substituted-1-alkenyl)boronic Esters
Brown, Herbert C.,Basavaiah, D.,Kulkarni, Surendra U.,Lee, Hsiupu D.,Negishi, Ei-ichi,Katz, Jean-Jacques
, p. 5270 - 5276 (2007/10/02)
Development of a general stereospecific synthesis of (E)-disubstituted alkenes utilizing a variety of hydroborating agents such as monohaloborane, thexylborane, thexylchloroborane, and dibromoborane is discussed.Hydroboration of 1-halo-1-alkynes with dial