26560-90-7Relevant articles and documents
An efficient method for the preparation of carboxamides by dehydration condensation using tetrakis(1,1,1,3,3,3-hexafluoro-2-propoxy)silane
Tozawa, Takashi,Yamane, Yoshinobu,Mukaiyama, Teruaki
, p. 1586 - 1587 (2005)
The use of tetraalkoxysilanes, particularly tetrakis(perfluoroalkoxy) silanes, in dehydration condensation of carboxylic acids with amines was investigated. Tetrakis(1,1,1,3,3,3-hexafluoro-2-propoxy)silane, Si[OCH(CF 3)2]4, prepared easily from silicon tetrachloride and sodium 1,1,1,3,3,3-hexafluoro-2-propoxide, was found to be an effective dehydrating reagent for preparing various carboxamides in good to high yields from the corresponding carboxylic acids and amines. Copyright