26603-20-3Relevant articles and documents
Linkage Effect in the Heterogenization of Cobalt Complexes by Doped Graphene for Electrocatalytic CO2 Reduction
Wang, Jiong,Huang, Xiang,Xi, Shibo,Lee, Jong-Min,Wang, Cheng,Du, Yonghua,Wang, Xin
, p. 13532 - 13539 (2019)
Immobilization of planar CoII-2,3-naphthalocyanine (NapCo) complexes onto doped graphene resulted in a heterogeneous molecular Co electrocatalyst that was active and selective to reduce CO2 into CO in aqueous solution. A systematic study revealed that graphitic sulfoxide and carboxyl dopants of graphene were the efficient binding sites for the immobilization of NapCo through axial coordination and resulted in active Co sites for CO2 reduction. Compared to carboxyl dopants, the sulfoxide dopants further improved the electron communication between NapCo and graphene, which led to the increase of turnover frequency of the Co sites by about 3 times for CO production with a Faradic efficiency up to 97 %. Pristine NapCo in the absence of a graphene support did not display efficient electron communication with the electrode and thus failed to serve as the electrochemical active site for CO2 reduction under the identical conditions.
Green pigment and use thereof
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Paragraph 0130-0131; 0134, (2020/03/23)
[Problem] weather resistance, heat resistance, stability and with a hygienic environment, after dispersion of colors of green pigment free halogen free, using paint, printing ink or toner and. General formula (1) compounds containing a green pigment [a]. [R1 , R6 , R7 , R12 , R13 , R18 , R19 , R24 Is, a hydrogen atom, R2 - R5 , R8 - R11 , R14 - R17 , R20 - R23 Is, a hydrogen atom, a cyano group, a nitro group, an alkyl group of 1 - 5 carbon atoms, an alkenyl group having a carbon number of 1 - 5, 6 - 10 carbon atoms of the aryl group, - OR25 , - COOR26 , - CONHR27 , - NHCOR28 , - SO2 NHR29 Or - NR30 R31 A, R25 - R31 Is, a hydrogen atom, an alkyl group of 1 - 5 carbon atoms, an alkenyl group having a carbon number of 1 - 5, 6 - 10 carbon atoms or aryl groups, X1 The ligands may have one hydrogen atom or 2 manganese, iron, cobalt, nickel, copper or zinc as shown. ] Figure 1 [drawing]