266363-17-1

Basic information

• Product Name: N-(2S,3R,4S,5S)-2,3,4,5,6-pentaacetoxyhexyl-1-yl-N-methyl-N'-phenylthiourea
• Synonyms: N-(2S,3R,4S,5S)-2,3,4,5,6-pentaacetoxyhexyl-1-yl-N-methyl-N'-phenylthiourea
• CAS NO: 266363-17-1
• Molecular Weight: 540.591
• Mol File: 266363-17-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2S,3R,4S,5S)-2,3,4,5,6-pentaacetoxyhexyl-1-yl-N-methyl-N'-phenylthiourea(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2S,3R,4S,5S)-2,3,4,5,6-pentaacetoxyhexyl-1-yl-N-methyl-N'-phenylthiourea(266363-17-1)
• EPA Substance Registry System: N-(2S,3R,4S,5S)-2,3,4,5,6-pentaacetoxyhexyl-1-yl-N-methyl-N'-phenylthiourea(266363-17-1)

Safety Data

• Hazardous Substances Data: 266363-17-1(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 266363-14-8 N-(2S,3R,4S,5S)-2,3,4,5,6-pentahydroxyhexyl-1-yl-N-methyl-N'-phenylthiourea 

Relevant articles and documents

[3+2]-cycloadditions of 2-aminothioisomunchnones to alkynes: Synthetic scope and mechanistic insights

This manuscript describes the regiospecific 1,3-dipolar cycloadditions of 2-aminothioisomunchnones (1-3) with methyl propiolate. The structure of compound 4 has been unequivocally determined by X-ray crystallography. Based on these experimental arguments and a theoretical rationale that supports the regiochemistry observed, a mechanistic pathway is discussed to account for the formation of pyridone or thiophene derivatives. The protocol has also been extended to the cycloadditions of aminothioisomunchnones derived from carbohydrates with dimethyl acetylenedicarboxylate to afford interesting glycosylaminoheterocycles. (C) 2000 Elsevier Science Ltd.