26650-09-9Relevant articles and documents
FONTIONNALISATION DES IODURES DE F-ALKYL-2 ETHANE PAR CATALYSE PAR TRANSFERT DE PHASE: IMPORTANCE DE CETTE TECHNIQUE EN SERIE F-ALKYLEE
Szonyi, F.,Cambon, A.
, p. 59 - 68 (1989)
F-alkyl-2 ethane iodides are very important starting materials in the field of organic chemistry.Their reactivity in homogeneous medium shows some drawbacks: reactions are uncomplete and resulting compounds are not pure.We resolved these problems using phase transfer catalysis and obtained outstanding results.F-alkyl-2 ethane iodides are strongly hydrophobic; so organic solvents are not necessary (water was used) and moreover the emulsions promoted during the reaction are not stable.
A new synthesis of alkane and polyfluoroalkanesulfonyl chlorides
Benfodda, Zohra,Guillen, Franck,Arnion, Helene,Dahmani, Abdelkader,Blancou, Hubert
experimental part, p. 355 - 361 (2010/07/16)
This study describes a new and advantageous procedure for the synthesis of alkanesulfonyl chlorides (2) by the reaction of alkyl thiocyanates (1) with sulfuryl chloride in a mixture of acetic acid and water. The alkanesulfonyl chlorides were obtained in good yields.
