26666-93-3Relevant articles and documents
Synthesis of labile all-trans-7,8,7′,8′-bis-acetylenic carotenoids by bi-directional Horner-Wadsworth-Emmons condensation
Vaz, Belén,Fontán, Noelia,Casti?eira, Marta,álvarez, Rosana,De Lera, ángel R.
, p. 3024 - 3031 (2015/03/18)
A new stereoselective synthesis of the C40-bis-acetylenic carotenoids all-trans-(3R,3′R)-alloxanthin and all-trans-3,4,7,8,3′,4′,7′,8′-octadehydro-β,β-carotene, both compounds featuring a stereochemically labile C7-C10 enyne, based on a bi-directional Horner-Wadsworth-Emmons (HWE) reaction of a C15-phosphonate and a central C10-dialdehyde, is reported. The triene unit of the latter fragment was synthesized using the acyclic metathesis/dimerization reaction.
Stereoselective total synthesis of the acetylenic carotenoids alloxanthin and triophaxanthin
Yamano, Yumiko,Chary, Mahankhali Venu,Wada, Akimori
, p. 4103 - 4108 (2012/06/15)
Stereoselective total synthesis of the C40-diacetylenic carotenoid alloxanthin (1) and the C31-acetylenic apocarotenoid triophaxanthin (2) was accomplished by Wittig condensation of C 10-dialdehyde 20 or C16-ket
Carotenoids and Related Compounds. Part 38. Synthesis of (3RS,3'RS)-Alloxanthin and Other Acetylenes
Davies, Anthony J.,Khare, Anakshi,Mallams, Alan K.,Massy-Westropp, Ralph A.,Moss, Gerard P.,Weedon, Basil C. L.
, p. 2147 - 2158 (2007/10/02)
The all-trans, 9-cis, and 9,9'-di-cis forms of (3RS,3'RS)-alloxanthin have been synthesized, also the 9-cis-isomer of (3RS,6'RS)-crocoxanthin.Perhydrogenation of alloxanthin gives a product with the same optical properties as perhydrozeaxanthin.These resu